Merck
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安全信息

D39002

Sigma-Aldrich

1,2-二溴苯

98%

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经验公式（希尔记法）:
C6H4Br2
CAS号:
583-53-9
分子量:
235.90
Beilstein:
970241
EC 号:
209-507-3
MDL编号:
MFCD00000057
PubChem化学物质编号:
24893794
NACRES:
NA.22

蒸汽密度

8.2 (vs air)

质量水平

200

检测方案

98%

形式

liquid

折射率

n20/D 1.611 (lit.)

bp

224 °C (lit.)

mp

4-6 °C (lit.)

密度

1.956 g/mL at 25 °C (lit.)

SMILES string

Brc1ccccc1Br

InChI

1S/C6H4Br2/c7-5-3-1-2-4-6(5)8/h1-4H

InChI key

WQONPSCCEXUXTQ-UHFFFAOYSA-N

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象形图

Exclamation markEnvironment
GHS07,GHS09

警示用语：

Warning

危险分类

Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

197.6 °F - closed cup

闪点(°C)

92 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Holger F Bettinger et al.
The Journal of organic chemistry, 72(25), 9750-9752 (2007-11-08)
The one-step high-yield synthesis of 1,2-bis(trimethylsilyl)benzene from 1,2-dibromobenzene using tert-butyllithium and trimethylsilyltriflate is reported. A mechanistic investigation shows that 1,2-dilithiobenzene is not an intermediate in this reaction; the coexistence of trimethylsilyltriflate and tert-butyllithium at very low temperatures allows a sequence
G Shakila et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 86, 449-455 (2011-11-25)
The FT-IR and FT-Raman spectra of the compound 1,2-dibromobenzene have been recorded in the region 4000-100cm(-1). The vibrational analysis has been made using HF and DFT (B3LYP and LSDA) level of theory by employing 6-31 +G (d, p) and 6-311
Jadwiga A Szymańska et al.
International journal of occupational medicine and environmental health, 15(4), 375-383 (2003-03-01)
The distribution, excretion and metabolism of 1,4-dibromobenzene (1,4-DBB) and 1,2-dibromobenzene (1,2-DBB), following a single intraperitoneal administration to female Wistar rats, were investigated using radiotracer 3H and GC-MS technique. The maximum level of 3H after 1,4-DBB administration was detected in all
Mónica Carril et al.
Organic letters, 7(22), 4787-4789 (2005-10-21)
[reaction: see text] A new route to oxcarbazepine (Trileptal), the most widely prescribed antiepileptic drug, starting from commercially available 2'-aminoacetophenone and 1,2-dibromobenzene, is reported. The sequentially accomplished key steps are palladium-catalyzed intermolecular alpha-arylation of ketone enolates and intramolecular N-arylation reactions.
J A Szymańska et al.
Journal of applied toxicology : JAT, 16(1), 35-41 (1996-01-01)
Various doses of dibromobenzene isomers (1,2-dBB, 1,3-dBB, 1,4-dBB) were administered (i.p.) to BALB mice. The levels of reduced glutathione (GSH) and malondialdehyde (MDA) in the liver, and glutamate-pyruvate transaminase (GPT) (EC.2.6.1.2) gamma-glutamyltransferase (gamma-GT) (EC.2.3.2.2) and triglycerides (TG) in the serum
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