D91071
苄基膦酸二乙酯
99%
别名:
NSC 62294, 苄基膦酸二乙酯, （二乙氧基膦甲基）苯
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关于此项目
线性分子式:
C6H5CH2P(O)(OC2H5)2
化学文摘社编号:
分子量:
228.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
214-097-4
MDL number:
产品名称
苄基膦酸二乙酯, 99%
InChI key
AIPRAPZUGUTQKX-UHFFFAOYSA-N
InChI
1S/C11H17O3P/c1-3-13-15(12,14-4-2)10-11-8-6-5-7-9-11/h5-9H,3-4,10H2,1-2H3
SMILES string
CCOP(=O)(Cc1ccccc1)OCC
assay
99%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.497 (lit.)
bp
106-108 °C/1 mmHg (lit.)
density
1.095 g/mL at 25 °C (lit.)
Quality Level
Application
用于合成以下物质的反应物：
用作以下过程的反应物：
- 3,5-二羟基-4-异丙基二苯乙烯（治疗皮肤疾病）
- 通过分子内 Diels-Alder 反应来源的天然细胞毒性海产品
- 邻二醇的柱上氧化和 Horner-Emmons 反应合成的二苯乙烯
- Wnt 通路抑制剂（使用 Wadsworth-Emmons 反应抑制结肠癌）
- 抗恶性疟原虫的抗疟药类似物
用作以下过程的反应物：
- 芳基醚、胺和酰胺的环化
- 研究官能团对线索有机发光二极管性能的影响
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Ananya Thomas et al.
Polymers, 12(8) (2020-08-17)
As a part of our ongoing investigations on passively fire protecting polymeric materials, we have been employing both reactive and additive routes involving phosphorus-containing compounds. These included inorganic and organic substances, and in the latter case, the phosphorus-bearing groups differed
Jack Saltiel et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(9), 2174-2179 (2019-05-28)
cis,trans-1,2-Dideuterio-1,4-diphenyl-1,3-butadiene (ct-DPBd2) was synthesized and its cis-trans photoisomerization in cyclohexane-d12 (C6D12) at room temperature was monitored by 1H NMR spectroscopy. The results reveal formation of only trans,trans-1,2-dideuterio-1,4-diphenyl-1,3-butadiene (tt-DPBd2). The failure to detect formation of trans,cis-1,2-dideuterio-1,4-diphenyl-1,3-butadiene (tc-DPBd2) eliminates the possibility that
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