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Merck
CN

E50604

乙基三苯基膦

99%

别名:

TEP

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关于此项目

线性分子式:
[(C6H5)3P+C2H5]Br-
化学文摘社编号:
1530-32-1
分子量:
371.25
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
24894599
EC Number:
216-223-3
Beilstein/REAXYS Number:
3599630
MDL number:
MFCD00011838

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产品名称

乙基三苯基膦, 99%

InChI key

JHYNXXDQQHTCHJ-UHFFFAOYSA-M

InChI

1S/C20H20P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1

SMILES string

[Br-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

assay

99%

reaction suitability

reaction type: C-C Bond Formation

mp

203-205 °C (lit.)

Quality Level

200

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相关类别

Application

用于合成以下物质的反应物：
  • L-半胱氨酸衍生的噻唑烷的 D-氨基酸
  • 通过 醛醇缩合反应和 Horner-Wadsworth-Emmons 烯化合成Leiodolide A
  • 通过非对映选择性分子内亚胺反应合成环烷二氢吲哚
  • 通过关键构件的结合来合成WXYZA的毒素的结构域

作为以下反应物：
  • 形成烷基二丙烯基噻吩单体的固态复分解缩聚
  • Mizoroki-Heck环化和级联Tsuji-Trost环化/内酯化环化反应，用于合成ABC环系统

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

401.0 °F

flash_point_c

205 °C

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCP9763
MKCK1634
MKBC7977V
MKBT2055V
MKBP1900V

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Rafał Oliwa
Materials (Basel, Switzerland), 13(17) (2020-08-28)
We investigated the effect of modified aluminosilicates, including bentonite from Armenia (BA) modified with quaternary ammonium salts (BAQAS) and phosphonium salts (BAQPS), on the mechanical properties and morphology of Kevlar/epoxy composites. The Kevlar/epoxy composites containing 1.0 or 3.0 wt.% modified
Airat Gubaev et al.
Nucleic acids research, 44(21), 10354-10366 (2016-08-26)
The topological state of DNA is important for replication, recombination and transcription, and is regulated in vivo by DNA topoisomerases. Gyrase introduces negative supercoils into DNA at the expense of ATP hydrolysis. It is the accepted view that gyrase achieves
Chris M Wood et al.
The Journal of experimental biology, 219(Pt 20), 3218-3226 (2016-11-02)
Nitrogen (N) appears to be a limiting dietary resource for elasmobranchs, required not only for protein growth but also for urea-based osmoregulation. Building on recent evidence that the toxicant ammonia can be taken up actively at the gills of the
Yoshihiro Noda et al.
Aging, 9(2), 556-572 (2017-02-18)
Gamma-aminobutyric acid (GABA)ergic and glutamatergic neurotransmissions in the prefrontal cortex decreases with age. Further, cognitive function mediated through the dorsolateral prefrontal cortex (DLPFC) also declines with age. Although neuroimaging studies have demonstrated decreased levels of these substances, direct neurophysiological data
Aru Panwar et al.
Otolaryngology--head and neck surgery : official journal of American Academy of Otolaryngology-Head and Neck Surgery, 158(1), 103-109 (2017-08-16)
Objectives To identify differences in postoperative wound complications associated with a primary tracheoesophageal puncture (TEP) at the time of laryngectomy versus no TEP. Study Design Retrospective review of large national data set. Setting Academic and nonacademic health care facilities in
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