Merck
CN

F17407

Sigma-Aldrich

1-甲酰哌啶

99%

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别名:
, NFP, 哌啶-1-甲醛
经验公式(希尔记法):
C6H11NO
CAS号:
分子量:
113.16
Beilstein:
107697
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

0.1 mmHg ( 25 °C)

质量水平

检测方案

99%

形式

liquid

折射率

n20/D 1.484 (lit.)

bp

222 °C (lit.)

密度

1.019 g/mL at 25 °C (lit.)

SMILES string

[H]C(=O)N1CCCCC1

InChI

1S/C6H11NO/c8-6-7-4-2-1-3-5-7/h6H,1-5H2

InChI key

FEWLNYSYJNLUOO-UHFFFAOYSA-N

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应用

反应物用于:
  • 过苯甲酸叔丁酯存在下通过无金属 C-H 活化直接酰胺化唑与甲酰胺
  • 三氯氧磷存在下吡唑与酰胺的 Vilsmeier 型反应
  • 醋酸钯和 Xantphos 催化 N-取代甲酰胺与芳基碘化物/溴化物共游离氨基羰基化合成芳基酰胺
  • 有机光伏用交替共聚物的合成
  • π-缺陷杂环锂试剂的一锅双官能化
  • 热稳定压致荧光聚集发射化合物的合成

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

闪点(°F)

215.6 °F - closed cup

闪点(°C)

102 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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