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Merck
CN

I19551

异戊二烯

99%, contains <1000 ppm p-tert-butylcatechol as inhibitor

别名:

2-甲基-1,3-丁二烯

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线性分子式:
CH2=CHC(CH3)=CH2
化学文摘社编号:
分子量:
68.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
969158
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产品名称

异戊二烯, 99%, contains <1000 ppm p-tert-butylcatechol as inhibitor

form

liquid

InChI key

RRHGJUQNOFWUDK-UHFFFAOYSA-N

SMILES string

CC(=C)C=C

InChI

1S/C5H8/c1-4-5(2)3/h4H,1-2H2,3H3

vapor density

2.35 (vs air)

vapor pressure

8.82 psi ( 20 °C)

assay

99%

autoignition temp.

428 °F

contains

<1000 ppm p-tert-butylcatechol as inhibitor

expl. lim.

10 %

refractive index

n20/D 1.422 (lit.)

bp

34 °C (lit.)

mp

−146 °C (lit.)

density

0.681 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

异戊二烯在作为引发剂的丁基锂的存在下,可以与苯乙烯和甲基丙烯酸甲酯进行顺序的阴离子聚合,从而形成聚苯乙烯-嵌段-聚异戊二烯-嵌段-聚(甲基丙烯酸甲酯)(SIM)和聚异戊二烯-嵌段-聚苯乙烯-嵌段-聚(甲基) 甲基丙烯酸酯(ISM),两种不对称三嵌段三元共聚物。它也可用于聚苯乙烯-嵌段-聚异戊二烯(PS-b-PI)二嵌段共聚物的不对称合成。

Packaging

pictograms

FlameHealth hazard

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 1 - Muta. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-65.2 °F - closed cup

flash_point_c

-54 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品
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分析证书(COA)

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Four-Phase Morphologies in Blends of ABC and BAC Triblock Terpolymers
Haenelt TG, et al.
Macromolecular Chemistry and Physics, 219(1), 1700241-1700241 (2018)
Morphology and elasticity of polystyrene-block-polyisoprene diblock copolymers in the melt.
Haenelt TG, et al.
Korea-Australia Rheology Journal, 26(3), 263-275 (2014)
Russell K Monson et al.
The New phytologist, 195(3), 541-559 (2012-06-29)
The leaves of many plants emit isoprene (2-methyl-1,3-butadiene) to the atmosphere, a process which has important ramifications for global and regional atmospheric chemistry. Quantitation of leaf isoprene emission and its response to environmental variation are described by empirically derived equations
Tomohisa Kuzuyama
Bioscience, biotechnology, and biochemistry, 66(8), 1619-1627 (2002-10-02)
Isoprenoids are synthesized by consecutive condensations of their five-carbon precursor, isopentenyl diphosphate, to its isomer, dimethylallyl diphosphate. Two pathways for these precursors are known. One is the mevalonate pathway, which operates in eucaryotes, archaebacteria, and cytosols of higher plants. The
Michaela Stieglmeier et al.
International journal of systematic and evolutionary microbiology, 64(Pt 8), 2738-2752 (2014-06-08)
A mesophilic, neutrophilic and aerobic, ammonia-oxidizing archaeon, strain EN76(T), was isolated from garden soil in Vienna (Austria). Cells were irregular cocci with a diameter of 0.6-0.9 µm and possessed archaella and archaeal pili as cell appendages. Electron microscopy also indicated

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