I7209
3-碘苯胺
98%
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线性分子式:
IC6H4NH2
化学文摘社编号:
分子量:
219.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-922-7
Beilstein/REAXYS Number:
636058
MDL number:
产品名称
3-碘苯胺, 98%
InChI key
FFCSRWGYGMRBGD-UHFFFAOYSA-N
InChI
1S/C6H6IN/c7-5-2-1-3-6(8)4-5/h1-4H,8H2
SMILES string
Nc1cccc(I)c1
assay
98%
form
liquid
refractive index
n20/D 1.682 (lit.)
bp
145-146 °C/15 mmHg (lit.)
mp
21-24 °C (lit.)
density
1.821 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Karsten Franke et al.
Environmental science & technology, 42(11), 4083-4087 (2008-07-02)
A new method is described for radiolabeling humic substances (HS) with iodine radioisotopes. The method radiolabels the electron-rich aromatic moieties of HS with the 3-[125I]iodobenzenediazonium ion via azocoupling. The method uses four steps: (i) 3-aminobenzenetrimethylstannane is synthesized and isolated by
Karin Dooleweerdt et al.
Organic letters, 11(1), 221-224 (2008-11-28)
A Pd-catalyzed, one-pot, two-step synthesis of 2-amidoindoles from ynamides and o-iodoanilines is reported. A key highlight of this sequence is that after the Sonogashira reaction, intramolecular cyclization to the indole occurs spontaneously without activation of the alkyne.
Toshio Nishikawa et al.
Bioscience, biotechnology, and biochemistry, 66(10), 2273-2278 (2002-11-27)
An alpha-C-iodoethynylglucose derivative was coupled with an L-serine-derived zinc-copper reagent to give alpha-C-glucosylpropargyl glycine, which underwent palladium catalyzed-heteroannulation with o-iodoaniline to give not alpha-C-glucosyl-tryptophan but alpha-C-glucosyl-iso-tryptophan. This is the first observation of complete reverse regioselectivity to Larock's proposal.
Fangguo Ye et al.
The Journal of organic chemistry, 72(9), 3218-3222 (2007-04-06)
The palladium-catalyzed cyclocarbonylation reaction of o-iodoanilines with allenes and CO in 1-butyl-3-methylimidazolium hexafluorophosphate afforded 3-methylene-2,3-dihydro-1H-quinolin-4-ones in moderate to excellent yields under a low pressure (5 atm) of CO. The ionic liquid, as the solvent and promoter, enhances the efficiency of
L A Khawli et al.
International journal of radiation applications and instrumentation. Part B, Nuclear medicine and biology, 19(3), 297-301 (1992-04-01)
Biotinyl-m-[125I]iodoanilide (BIA) was synthesized by coupling biotin to m-[125I]iodoaniline via a mixed anhydride reaction. m-[125I]Iodoaniline was produced from the tin precursor, which was prepared using a palladium catalyzed reaction of hexabutylditin with m-bromoaniline. The radioiodinated BIA derivative is characterized by
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