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线性分子式:
NaH2PO2 · H2O
化学文摘社编号:
分子量:
105.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-669-9
MDL number:
Assay:
≥99%
Form:
powder, crystals or chunks
InChI key
PLZNPHDJGFDNRM-UHFFFAOYSA-M
InChI
1S/Na.H3O2P.H2O/c;1-3-2;/h;3H2,(H,1,2);1H2/q+1;;/p-1
SMILES string
O.[Na+].[O-][PH2]=O
assay
≥99%
form
powder, crystals or chunks
pH
(6,0 - 8,0 at 50 g/l at 25 °C (77 °F))
solubility
water: 100 mg/mL, clear, colorless
Quality Level
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Application
次磷酸钠一水合物可用作
- :微波辐射下由四水合乙酸镍合成镍纳米粒子(NiNP)的还原剂。
- 在存在钌催化剂的条件下,将脂肪族和芳香族酮对映选择性转移氢化为相应醇的氢供体。
- 以N,N-甲基甲酰胺(DMF)为溶剂,催化废谷物酯化反应,以提高重金属离子吸附能力的催化剂。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Biphasic Glycerol/2-MeTHF, Ruthenium-Catalysed Enantioselective Transfer Hydrogenation of Ketones Using Sodium Hypophosphite as Hydrogen Donor.
Guyon C, et al.
European Journal of Organic Chemistry, 2013(24), 5439-5444 (2013)
Microwave assisted greener synthesis of nickel nanoparticles using sodium hypophosphite.
Eluri R and Paul B
Materials Letters, 76, 36-39 (2012)
Fast esterification of spent grain for enhanced heavy metal ions adsorption.
Li Q, et al.
Bioresource Technology, 101(10), 3796-3799 (2010)
Lukas J Goossen et al.
Chemical communications (Cambridge, England), (8)(8), 836-837 (2002-07-19)
A catalyst generated in situ from palladium acetate and tricyclohexylphosphine efficiently catalyzes the reduction of carboxylic acids with sodium hypophosphite in the presence of pivalic anhydride to give aldehydes with high selectivity. The low cost and convenient handling of the
W S Price et al.
Biophysical chemistry, 33(3), 205-215 (1989-07-01)
A 31P-NMR method, which complements earlier 13C-NMR procedures for probing the intra-erythrocyte microenvironment, is described. Hypophosphite is an almost unique probe of the erythrocyte microenvironment, since it is rapidly transported into the cell via the band 3 protein, and intra-
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