蒸汽压
5.09 psi ( 20 °C)
质量水平
方案
97%
折射率
n20/D 1.388-1.396
n20/D 1.392 (lit.)
沸点
50 °C (lit.)
密度
0.893 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C1COC1
InChI
1S/C3H6O/c1-2-4-3-1/h1-3H2
InChI key
AHHWIHXENZJRFG-UHFFFAOYSA-N
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应用
- Trimethylene oxide is a strained cyclic ether which can be used to replace carbonyl / gem-dimethyl groups during molecular modelling of bioactive molecules.
- It can be incorporated in various bioactive molecule and drug substances for its improved physicochemical properties, via novel C-H activation methods.
- Trimethylene oxide can also be used in the synthesis of poly(trimethylene oxide) and related polymer electrolytes.
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-4.0 °F - closed cup
闪点(°C)
-20 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Role of polar side chains in Li+ coordination and transport properties of polyoxetane-based polymer electrolytes.
Sai R, et al.
Physical Chemistry Chemical Physics, 19(7), 5185-5194 (2017)
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Steroids, 77(14), 1523-1529 (2012-09-18)
Catalytic hydrogenation is extensively used in steroid chemistry. The interest in transformations to the steroid skeleton of ecdysteroids has been increasing in the past years. Essential interest in the chemistry of ecdysteroids is caused by the selective reduction of Δ7
Complex bioactive alkaloid-type polycycles through efficient catalytic asymmetric multicomponent aza-Diels-Alder reaction of indoles with oxetane as directing group.
Zhilong Chen et al.
Angewandte Chemie (International ed. in English), 52(7), 2027-2031 (2013-01-11)
Chun-Bao Miao et al.
The Journal of organic chemistry, 76(23), 9809-9816 (2011-10-27)
An efficient base-controlled selective conversion of the Michael adducts of malonates with enones in the presence of iodine is reported. Highly functionalized cyclopropane, oxetane, and α-hydroxylmalonate derivatives are obtained selectively using DBU, Na(2)CO(3), and NaOAc as the base, respectively. O(2)
Luciana Capece et al.
The journal of physical chemistry. B, 116(4), 1401-1413 (2011-12-27)
Indoleamine 2,3-dioxygenase (IDO) and tryptophan dioxygenase (TDO) are two heme proteins that catalyze the oxidation reaction of tryptophan (Trp) to N-formylkynurenine (NFK). Human IDO (hIDO) has recently been recognized as a potent anticancer drug target, a fact that triggered intense
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