15230
[双(三氟乙酰氧基)碘]苯
purum, ≥95.0% (AT)
别名:
I,I-双(三氟乙酸)碘苯, BTI, PIFA
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关于此项目
线性分子式:
(CF3CO2)2IC6H5
化学文摘社编号:
分子量:
430.04
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-308-0
Beilstein/REAXYS Number:
764767
MDL number:
产品名称
[双(三氟乙酰氧基)碘]苯, purum, ≥95.0% (AT)
InChI key
PEZNEXFPRSOYPL-UHFFFAOYSA-N
InChI
1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H
SMILES string
FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1
grade
purum
assay
≥95.0% (AT)
form
solid
reaction suitability
reagent type: oxidant
mp
121-125 °C (lit.)
122-125 °C
functional group
fluoro
iodo
Quality Level
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Application
反应物或试剂用于：
- Pummerer 类反应
- 二甲氧基苄基醚的化学选择性脱保护
- 介导氧化环异构化
- 苯胺类的甲氧基化
Other Notes
用于脱氢和氧化反应的试剂，综述；酰胺直接转化成胺（Hofmann-型重排反应）的新型试剂，以及羧基端多肽测序的关键物质；也可用于羰基的平稳脱硫缩醛化反应
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
M.R. Almond et al.
Organic Syntheses, 66, 132-132 (1988)
G. Stork et al.
Tetrahedron Letters, 30, 287-287 (1989)
A. Varvoglis
Synthesis, 709-709 (1984)
William C Skarnes et al.
Methods (San Diego, Calif.), 164-165, 18-28 (2019-06-20)
The generation of induced pluripotent stem cell models of human disease requires efficient modification of one or both alleles depending on dominant or recessive inheritance of the disease. To faithfully recapitulate many disease variants, the introduction of a single base
Determination of asparagine and glutamine in polypeptides using bis(I,I-trifluoroacetoxy)iodobenzene.
L M Soby et al.
Analytical biochemistry, 113(1), 149-153 (1981-05-01)
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