Merck
CN

179922

Sigma-Aldrich

邻苯二甲酸氢钾

ACS reagent, acidimetric standard

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别名:
KHP, 苯二甲酸氢钾, 邻苯二甲酸 单钾盐, 酞酸氢钾
线性分子式:
HOOCC6H4COOK
CAS号:
分子量:
204.22
Beilstein:
3637128
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.21

等级

ACS reagent

质量水平

检测方案

99.95-100.05% dry basis

形式

crystals

质量

acidimetric standard

杂质

≤0.002% S compounds
≤0.003% Cl compounds
≤0.005% insolubles

pH值(酸碱度)

4.00-4.02 (25.0 °C±0.2 °C, 0.05 M)

mp

295-300 °C (dec.) (lit.)

痕量阳离子

Fe: ≤5 ppm
Na: ≤0.005%
heavy metals: ≤5 ppm (by ICP)

SMILES string

[K+].OC(=O)c1ccccc1C([O-])=O

InChI

1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1

InChI key

IWZKICVEHNUQTL-UHFFFAOYSA-M

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应用

邻苯二甲酸氢钾可用作酸量滴定的一级标准品,也可用于制备用于 pH 校准的邻苯二甲酸氢钾缓冲液。

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

闪点(°F)

387.1 °F - Pensky-Martens closed cup

闪点(°C)

197.3 °C - Pensky-Martens closed cup

个人防护装备

Eyeshields, Gloves, type N95 (US)


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2, 4, 6-Trinitrobenzoic acid as a primary standerd in acidimetry.
Smith GF and Wilkins DH.
Analytica Chimica Acta, 8, 209-216 (1953)
Determination of standard pH values for potassium hydrogen phthalate reference buffer solutions in 10, 20, 50, 64 and 84.2 wt per cent methanol/water mixed solvents at temperatures from 283.15 to 313.15 K.
Mussini T, et al.
Electrochimica Acta, 28(11), 1593-1598 (1983)
J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
Maria Cristina Fossi et al.
Marine pollution bulletin, 64(11), 2374-2379 (2012-09-12)
Baleen whales are potentially exposed to micro-litter ingestion as a result of their filter-feeding activity. However, the impacts of microplastics on baleen whales are largely unknown. In this case study of the Mediterranean fin whale (Balaenoptera physalus), we explore the
Hanne Frederiksen et al.
Environmental science & technology, 47(2), 958-967 (2012-12-14)
Urinary phthalate excretion is used as marker of phthalate exposure in epidemiological studies. Here we examine the reliability of urinary phthalate levels in exposure classification by comparing the inter- and intrasubject variation of urinary phthalate metabolite levels. Thirty-three young healthy

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