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Merck
CN

228036

OXONE®,单过硫酸盐化合物

别名:

单过硫酸氢钾

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关于此项目

线性分子式:
KHSO5 · 0.5KHSO4 · 0.5K2SO4
化学文摘社编号:
分子量:
307.38
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Form:
powder
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vapor pressure

<0.0000017 hPa

Quality Level

form

powder

reaction suitability

reagent type: oxidant

concentration

>4.0% (active oxygen basis (by Na2S2O3, titration))

pH

2.1 (77 °C, 30 g/L)

SMILES string

[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O

InChI

1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

HJKYXKSLRZKNSI-UHFFFAOYSA-I

General description

OXONE®单过硫酸钾氧酮是一种钾三元盐,主要用作稳定、易处理、无毒的氧化剂。

Application

据报道,使用缓冲的 OXONE 可以快速有效地从亚胺合成氧氮杂环丙烷。也用于研究美术颜料的褪色。
OXONE®单过硫酸盐化合物可作为过渡金属氧化剂的替代品,用于将醛类转化为羧酸或酯类。
用于卤化α,β不饱和羰基化合物和催化生成用于酒精氧化的高价碘试剂的氧化剂。

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis


Atmos. Environ., Part A, 27A, 765-765 (1993)
Yifu Li et al.
Bioresource technology, 262, 294-301 (2018-05-08)
In this study, zero valent iron (ZVI) activated peroxymonosulfate (PMS) as novel technique (i.e. ZVI-PMS technology) was employed to enhance sludge dewatering. In optimal sludge dewatering conditions of ZVI and KHSO5 dosages, the specific resistance to filtration (SRF) was reduced
J Rodríguez-Chueca et al.
Journal of hazardous materials, 372, 94-102 (2018-05-08)
This study explores the enhancement of UV-C tertiary treatment by sulfate radical based Advanced Oxidation Processes (SR-AOPs), including photolytic activation of peroxymonosulfate (PMS) and persulfate (PS) and their photocatalytic activation using Fe(II). Their efficiency was assessed both for the inactivation



全球贸易项目编号

货号GTIN
228036-1KG04061838781178
228036-25KG04061835561773
228036-5G04061838781185
228036-100G04061838781161
228036-5KG04061832579290