228036
OXONE®，单过硫酸盐化合物
别名:
单过硫酸氢钾
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关于此项目
线性分子式:
KHSO5 · 0.5KHSO4 · 0.5K2SO4
化学文摘社编号:
分子量:
307.38
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
蒸汽压
<0.0000017 hPa
质量水平
表单
powder
反应适用性
reagent type: oxidant
浓度
>4.0% (active oxygen basis (by Na2S2O3, titration))
pH值（酸碱度）
2.1 (77 °C, 30 g/L)
SMILES字符串
[K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O.O[S+]([O-])([O-])(=O)=O
InChI
1S/5K.2H2O5S.2H2O4S/c;;;;;2*1-5-6(2,3)4;2*1-5(2,3)4/h;;;;;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
InChI key
HJKYXKSLRZKNSI-UHFFFAOYSA-I
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一般描述
OXONE®单过硫酸钾氧酮是一种钾三元盐，主要用作稳定、易处理、无毒的氧化剂。
应用
OXONE®单过硫酸盐化合物可作为过渡金属氧化剂的替代品，用于将醛类转化为羧酸或酯类。
据报道，使用缓冲的 OXONE 可以快速有效地从亚胺合成氧氮杂环丙烷。也用于研究美术颜料的褪色。
用于卤化α,β不饱和羰基化合物和催化生成用于酒精氧化的高价碘试剂的氧化剂。
用于卤化a、b不饱和羰基化合物的氧化剂和催化生成用于酒精氧化高价碘试剂的氧化剂。
2-碘氧基苯磺酸是一种非常活跃的催化剂，可选择性地将醇氧化为醛、酮、羧酸和烯酮与过氧单磺酸钾反应
α，β-不饱和羰基化合物与过氧单磺酸钾®和氢卤酸(HBr, HCl)的便捷卤化反应
2-碘氧基苯磺酸是一种非常活跃的催化剂，可选择性地将醇氧化为醛、酮、羧酸和烯酮与过氧单磺酸钾反应
α，β-不饱和羰基化合物与过氧单磺酸钾®和氢卤酸(HBr, HCl)的便捷卤化反应
法律信息
OXONE is a registered trademark of E. I. du Pont de Nemours and Company
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Atmos. Environ., Part A, 27A, 765-765 (1993)
Yifu Li et al.
Bioresource technology, 262, 294-301 (2018-05-08)
In this study, zero valent iron (ZVI) activated peroxymonosulfate (PMS) as novel technique (i.e. ZVI-PMS technology) was employed to enhance sludge dewatering. In optimal sludge dewatering conditions of ZVI and KHSO5 dosages, the specific resistance to filtration (SRF) was reduced
Jiamin Hu et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 79(5), 911-920 (2019-04-27)
In this study, the difference in oxidative capacity for removing antibiotics and the mechanism between the Cu(II)/peroxymonosulfate (PMS)/UV and Cu(II)/persulfate (PDS)/UV systems were compared under various conditions. The optimal Cu(II) concentration in the Cu(II)/PMS/UV system was 30 μM, and in
Masami Fukushima et al.
Chemosphere, 80(8), 860-865 (2010-06-19)
Tetrabromobisphenol A (TBBPA), a commercially used brominated flame retardant, also functions as an endocrine disruptor and is of serious concern in terms of environmental pollution. TBBPA has been detected in leachates from landfills, because hydrophobic interactions with humic acids (HAs)
Raf Dewil et al.
Journal of hazardous materials, 146(3), 577-581 (2007-05-29)
During the anaerobic digestion of wastewater treatment sludge, commonly called biosolids, an energy rich biogas is formed which is now considered as renewable energy source and widely used for the production of heat and/or electricity. Pre-treatment methods, which achieve a
商品
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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