33152
1,5-二苯卡巴肼
reag. Ph. Eur., ≥98.0%
别名:
1,5-二苯羰酰肼, 对称二苯氨基脲
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关于此项目
线性分子式:
C6H5NHNHCONHNHC6H5
化学文摘社编号:
分子量:
242.28
UNSPSC Code:
41116105
NACRES:
NA.21
PubChem Substance ID:
EC Number:
205-403-7
Beilstein/REAXYS Number:
752039
MDL number:
产品名称
1,5-二苯卡巴肼, reag. Ph. Eur., ≥98.0%
InChI key
KSPIHGBHKVISFI-UHFFFAOYSA-N
InChI
1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)
SMILES string
O=C(NNc1ccccc1)NNc2ccccc2
agency
USP/NF
reag. Ph. Eur.
assay
≥98% (HPLC)
≥98.0%
technique(s)
UV/Vis spectroscopy: suitable
titration: suitable
impurities
diphenylcarbazone, in accordance
≤0.1% insoluble matter in ethanol
ign. residue
≤0.05% (as SO4)
mp
170-175 °C (lit.)
170-175 °C
suitability
passes test for Hg detection
Quality Level
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Application
在利用滴滤器还原生物铬（VI）的实验过程中，1,5-二苯卡巴肼被用于制备二苯卡巴肼溶液。在在线预浓缩和测定水中的痕量铬（VI）时，它可用于HPLC的柱前络合。
General description
1,5-二苯卡巴肼与铬（VI）反应，已被广泛用于铬的分光光度法测定。它也是一种电子供体，可用于测量亚叶绿体碎片中的光系统2活性。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
On-line preconcentration and determination of chromium (VI) in waters by high-performance liquid chromatography using pre-column complexation with 1, 5-diphenylcarbazide.
Padarauskas A
Journal of Chromatography A, 808 (1), 193-199 (1998)
Biological chromium (VI) reduction using a trickling filter.
Dermou E
Journal of Hazardous Materials, 126 (1), 78-85 (2005)
Oxidation of 1, 5-diphenylcarbazide as a measure of photosystem 2 activity in subchloroplast fragments.
Vernon LP and Shaw ER.
Biochemical and Biophysical Research Communications, 36 (6), 878-884 (1969)
W Hillier et al.
Biochemistry, 36(1), 76-85 (1997-01-07)
The behavior of photosystem II (PSII) reactions was investigated under conditions of decreasing water content by the addition of increasing concentrations of ethylene glycol (EG). The photosynthetic activities were measured for PSII samples either directly in aqueous solutions of EG
G Samanta et al.
Analytical chemistry, 73(9), 2034-2040 (2001-05-17)
An automated continuous instrument for the collection and measurement of aerosol Cr(VI) is described. The system alternately collects the sample on one of two glass fiber filters. After 15-min sample collection on one filter, the sampling switches over to the
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