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安全信息

39380

Sigma-Aldrich

3-二甲氨基-1-丙胺

purum, ≥98.0% (GC)

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别名:
N,N-二甲基-1,3-丙二胺, N,N-二甲基-1,3-二氨基丙烷
线性分子式:
(CH3)2N(CH2)3NH2
CAS号:
109-55-7
分子量:
102.18
Beilstein:
605293
EC 号:
203-680-9
MDL编号:
MFCD00008216
PubChem化学物质编号:
329755864
NACRES:
NA.22

蒸汽密度

3.6 (vs air)

质量水平

200

蒸汽压

5 mmHg ( 20 °C)

等级

purum

检测方案

≥98.0% (GC)

形式

liquid

杂质

≤2% water

折射率

n20/D 1.435 (lit.)
n20/D 1.436

bp

133 °C (lit.)

密度

0.812 g/mL at 25 °C (lit.)

SMILES string

CN(C)CCCN

InChI

1S/C5H14N2/c1-7(2)5-3-4-6/h3-6H2,1-2H3

InChI key

IUNMPGNGSSIWFP-UHFFFAOYSA-N

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相关类别

一般描述

3-(Dimethylamino)-1-propylamine (DMAPA, N,N-dimethyl-1,3-propanediamine) is a dialkylamino alkyl amine. It has been prepared from dimethylamine and acrylonitrile and confirmed by 1H NMR. It participates in the synthesis of bio-based zwitterionic surfactants from waste cooking oil (WCO).

应用

3-(Dimethylamino)-1-propylamine (DMAPA) is suitable reagent used in the following studies:
  • As a cationic moiety to form the ionic liquid, 3-(dimethylamino)-1-propylaminium formate ([DMAPA]FA) which is a potential reagent to extract protein from yeast cells.
  • As an aminating agent in the palladium-catalyzed amination of aryl amines.
  • In the derivatization of pullulan to form cationic pullulan.
  • In the partial modification of poly(styrene-alt-maleic anhydride) to form N-substituted maleimide.
  • As a test compound in the parallel synthesis of alkylamine lipidoids.
  • To cleave the polyamides synthesized by solid phase methods on Boc-β-Ala-PAM resin.
It may be used in the following studies:
  • Synthesis of (N,N-dialkylamino)alkyl-2-amino benzamide by reacting with isatoic anhydride.
  • As a reagent for the anomeric deacetylation of protected sugars.
  • Preparation of bioreducible copolymers used in gene delivery.

其他说明

工业用途

警示用语：

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

89.6 °F - closed cup

闪点(°C)

32 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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A Comprehensive Mechanism for Aromatic Nucleophilic Substitution in Aprotic Solvents: Derivation of the Whole Reaction Scheme for Third Order in Amine Kinetic Law.
Alvaro CE, et al.
Physical Chemistry, 3(2), 39-47 (2013)
Liya Ge et al.
Talanta, 81(4-5), 1861-1864 (2010-05-06)
As the first attempt, ionic liquid solutions have been employed for direct extraction of proteins from yeast cells. Compared with effects of 21 different ionic liquid solutions on the extraction efficiency, 3-(dimethylamino)-1-propylaminium formate ([DMAPA]FA) was selected as the suitable ionic
Linxian Li et al.
Bioconjugate chemistry, 24(9), 1543-1551 (2013-08-06)
Efficient delivery of plasmid DNA and siRNA into cells is essential for biological and biomedical research. Although significant efforts have been made to develop efficient nonviral vectors, such as cationic lipids and polymers, most of the vectors require multistep synthesis
Exploring the potential of xanthene derivatives as trypanothione reductase inhibitors and chloroquine potentiating agents.
Chibale K, et al
Tetrahedron, 59(13), 2289-2296 (2003)
New antihistaminic agents: Synthesis and evaluation of h 1-antihistaminic actions of 3-[(N,N-dialkylamino) alkyl)-1, 2, 3, 4-tetrahydro-(1H)-thioquinazolin-4 (3H)-ones and their oxo analogues.
Raju MB, et al
Indian Journal of Pharmaceutical Sciences, 69(6), 853-853 (2007)
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