426318
四甲基氢氧化铵 溶液
1.0 M±0.02 M in H₂O, solution, ACS reagent grade
别名:
N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH
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关于此项目
线性分子式:
(CH3)4N(OH)
化学文摘社编号:
分子量:
91.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3558708
产品名称
四甲基氢氧化铵 溶液, ACS reagent
InChI
1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1
SMILES string
[OH-].C[N+](C)(C)C
InChI key
WGTYBPLFGIVFAS-UHFFFAOYSA-M
grade
ACS reagent
form
liquid
concentration
1.0 M±0.02 M in H2O
ign. residue
≤5 ppm
color
APHA: ≤10
refractive index
n20/D 1.3497
bp
100 °C
density
1.005 g/mL at 25 °C
anion traces
chloride (Cl-): ≤0.03%
cation traces
K: ≤2 ppm
Na: ≤2 ppm
functional group
amine
Quality Level
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Application
四甲基氢氧化铵溶液可用作：
- 试剂，通过有机催化光诱导桦木还原将芳烃转换为 1,4-环己二烯。
- 催化剂，通过 2-萘酚、芳香醛和尿素的一锅三组分缩合反应合成1,2-二氢-1-芳基萘-恶嗪-3- 1衍生物。
- 磁性纳米颗粒的助剂，以提高排斥力的稳定性。
- 模板，利用热液合成法生成不同大小的分级沸石 T 聚合物。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Dermal - STOT SE 2
target_organs
Central nervous system, Liver,thymus
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Lulu Xie et al.
Science (New York, N.Y.), 342(6156), 373-377 (2013-10-19)
The conservation of sleep across all animal species suggests that sleep serves a vital function. We here report that sleep has a critical function in ensuring metabolic homeostasis. Using real-time assessments of tetramethylammonium diffusion and two-photon imaging in live mice
Lina Barreto et al.
Eukaryotic cell, 10(9), 1241-1250 (2011-07-05)
Potassium homeostasis is crucial for living cells. In the yeast Saccharomyces cerevisiae, the uptake of potassium is driven by the electrochemical gradient generated by the Pma1 H(+)-ATPase, and this process represents a major consumer of the gradient. We considered that
Qin Chen et al.
Bioresource technology, 117, 186-192 (2012-05-23)
The aim of this study was to explore the synergies of laccase, a ligninolytic enzyme, with cellulose and hemicellulase amendments on ensiled corn stover. Molecular signals of lignin decomposition were observed by tetramethylammonium hydroxide thermochemolysis and gas chromatography-mass spectroscopy (TMAH-GC-MS)
Konrad Rykaczewski et al.
Langmuir : the ACS journal of surfaces and colloids, 29(3), 881-891 (2012-12-25)
The prospect of enhancing the condensation rate by decreasing the maximum drop departure diameter significantly below the capillary length through spontaneous drop motion has generated significant interest in condensation on superhydrophobic surfaces (SHS). The mobile coalescence leading to spontaneous drop
Marta Matvienko et al.
PloS one, 8(2), e55913-e55913 (2013-02-15)
Several applications of high throughput genome and transcriptome sequencing would benefit from a reduction of the high-copy-number sequences in the libraries being sequenced and analyzed, particularly when applied to species with large genomes. We adapted and analyzed the consequences of
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