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Merck
CN

77848

(R)-(+)-1-苯基乙醇

derivatization grade (chiral), LiChropur™, ≥99.0%

别名:

(+)-甲基苯基甲醇, (R)-(+)-α-甲基苯甲醇

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关于此项目

经验公式（希尔记法）:
C8H10O
化学文摘社编号:
1517-69-7
分子量:
122.16
UNSPSC Code:
12352200
NACRES:
NA.05
PubChem Substance ID:
329767971
MDL number:
MFCD00064263
Beilstein/REAXYS Number:
2039798

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产品名称

(R)-(+)-1-苯基乙醇, derivatization grade (chiral), LiChropur™, ≥99.0%

InChI

1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-/m1/s1

SMILES string

C[C@@H](O)c1ccccc1

InChI key

WAPNOHKVXSQRPX-SSDOTTSWSA-N

grade

derivatization grade (chiral)

product line

ChiraSelect™

assay

≥99.0% (sum of enantiomers, GC)
≥99.0%

form

liquid

optical activity

[α]20/D +45±1°, c = 5% in methanol

optical purity

enantiomeric ratio: ≥99.5:0.5 (GC)

quality

LiChropur™

technique(s)

HPLC: suitable

refractive index

n20/D 1.528

bp

88-89 °C/10 mmHg (lit.)

mp

9-11 °C (lit.)

density

1.012 g/mL at 20 °C (lit.)

Quality Level

100

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Other Notes

于检测对映体纯度和分离酸的手性试剂；环酐和环氧化物的不对称开环
Discover LiChropur reagents ideal for HPLC or LC-MS analysis

General description

(R)-(+)-1-Phenylethanol is a chiral derivatizating agent, which is employed for derivatizing acids for their subsequent analysis using gas chromatography as the analytical technique.

Legal Information

ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number
BCBX0029

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S.V. Ley et al.
Tetrahedron, 46, 4995-4995 (1990)
Y. Takeuchi et al.
Journal of the Chemical Society. Perkin Transactions 1, 2203-2203 (1987)
T. Rosen et al.
Journal of the American Chemical Society, 107, 3731-3731 (1985)
H. Niwa et al.
Tetrahedron Letters, 29, 5139-5139 (1988)
Sachiko Sugimoto et al.
Phytochemistry, 108, 189-195 (2014-12-03)
Three aromatic glycosides (1-3), two sulfur and nitrogen-containing compound glucosides (4, 5), and one flavonoid glycoside (6) were isolated from the leaves of Ixora undulata. Their structures were established by extensive 1D, 2D NMR, and HRESIMS experiments, and structure 4

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