Structure-activity effects in peptide self-assembly and gelation - Dendritic versus linear architectures.

Structure-activity effects in peptide self-assembly and gelation - Dendritic versus linear architectures.

Chemical communications (Cambridge, England) (2012-07-05)

Cecile A Lagadec, David K Smith

摘要

We demonstrate that linear-dendritic shape-isomerism can have an impact on the gelation potential of peptides based on lysine, but the architectural effects can be inverted depending on the choice of functional groups, with the nature of these protecting groups dominating the gelation ability.

材料

Product Number

品牌

产品描述

D56802

Sigma-Aldrich

1,2-二氯苯, ReagentPlus^®, 99%

270598

Sigma-Aldrich

1,2-二氯苯, suitable for HPLC, 99%

240664

Sigma-Aldrich

1,2-二氯苯, anhydrous, 99%

36707

Supelco

1,2-二氯苯, PESTANAL^®, analytical standard

612510

Sigma-Aldrich

1,2-二氯苯溶液, suitable for NMR (reference standard), 5% in acetone-d₆ (99.9 atom % D), NMR tube size 5 mm × 8 in.