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线性分子式:
FeCl3 · 6H2O
化学文摘社编号:
分子量:
270.30
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-729-4
MDL number:
Assay:
98.0-102% (RT)
Form:
crystals or chunks
form
crystals or chunks
InChI key
NQXWGWZJXJUMQB-UHFFFAOYSA-K
InChI
1S/3ClH.Fe.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3
SMILES string
O.O.O.O.O.O.Cl[Fe](Cl)Cl
grade
ACS reagent, puriss. p.a.
vapor pressure
1 mmHg ( 194 °C)
assay
98.0-102% (RT)
quality
crystallized
impurities
≤0.001% total nitrogen (N), ≤0.002% free chlorine (Cl), ≤0.01% phosphorous compounds (as PO4)
bp
280-285 °C (lit.)
mp
37 °C (lit.)
anion traces
nitrate (NO3-): ≤100 mg/kg, sulfate (SO42-): ≤50 mg/kg
cation traces
As: ≤5 mg/kg, Ca: ≤50 mg/kg, Cd: ≤10 mg/kg, Co: ≤50 mg/kg, Cr: ≤100 mg/kg, Cu: ≤20 mg/kg, Fe2+: ≤20 mg/kg, K: ≤50 mg/kg, Mg: ≤10 mg/kg, Mn: ≤1000 mg/kg, Na: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤20 mg/kg, Zn: ≤20 mg/kg
Quality Level
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General description
六水三氯化铁可以通过三氯化铁水溶液结晶而获得。六水三氯化铁晶体结构的三维单晶X射线衍射研究表明其晶体为单斜晶系和 C2h3-2/m 空间群。
Application
六水三氯化铁(FeCl3.6H2O)可用作以下转化过程的氧化剂:
- 合成2-取代的4(3H)-喹唑啉酮(产率= 77-93%)。
- 将1,4-二氢吡啶(1,4-DHP)氧化成相应的吡啶。
- 将4-异丙基-1,4-DHP氧化成脱烷基化吡啶。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
危险化学品
此项目有
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Lu J, et al.
Synthetic Communications, 31(17), 2625-2630 (2001)
Benign and efficient synthesis of 2-substituted 4(3H)-quinazolinones mediated by iron (III) chloride hexahydrate in refluxing water.
Wang G-W, et al.
Bulletin of the Chemical Society of Japan, 79(9), 1426-1430 (2006)
Crystal structure of ferric chloride hexahydrate.
Lind MD.
J. Chem. Phys. , 47(3), 990-993 (1967)
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