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Merck
CN

710733

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

Synonym(s):

1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide

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About This Item

Empirical Formula (Hill Notation):
C14H22NO
CAS Number:
Molecular Weight:
220.33
UNSPSC Code:
12162002
PubChem Substance ID:
MDL number:
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InChI

1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3

SMILES string

CC(C)C(N([O])C(C)(C)C)c1ccccc1

InChI key

VGHCMXLEZFMZOZ-UHFFFAOYSA-N

refractive index

n20/D 1.515

density

0.953 g/mL at 25 °C

storage temp.

−20°C

Application

Stable nitroxide radical useful in controlling living radical polymerizations

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

pictograms

Flame over circleSkull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Ox. Liq. 3

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

205.0 °F - closed cup

flash_point_c

96.1 °C - closed cup


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Articles

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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