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Merck
CN

919772

Sigma-Aldrich

Tris(dibenzylideneacetone)dipalladium(0) ChemBeads

solid

别名:

Pd2dba3, Pd2(dba)3

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About This Item

线性分子式:
(C6H5CH=CHCOCH=CHC6H5)3Pd2
CAS Number:
分子量:
915.72
MDL编号:
UNSPSC代码:
12161600
NACRES:
NA.22

Product Name

Tris(dibenzylideneacetone)dipalladium(0) ChemBeads,

表单

solid

质量水平

组成

~ 5 wt.% loading of catalyst

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

储存温度

2-8°C

SMILES字符串

O=C(/C=C/c1ccccc1)/C=C/c2ccccc2.O=C(/C=C/c3ccccc3)/C=C/c4ccccc4.O=C(/C=C/c5ccccc5)/C=C/c6ccccc6.[Pd].[Pd]

InChI

1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;

InChI key

CYPYTURSJDMMMP-WVCUSYJESA-N

应用

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
  • Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
  • Preparation of palladium triphenylphosphine carbonyl cluster complexes
  • Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
  • Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes

Catalyst for:
  • Suzuki cross-coupling reactions
  • PCN- and PCS-pincer palladium complex catalyzed tandem allylation
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for C-C and C-N bond formation especially Suzuki, Heck coupling reaction

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
Learn more about ChemBeads products
For larger scale uses, product also available in powdered form (328774)

法律信息

Tris(dibenzylideneacetone)dipalladium(0) is Product of Umicore

Additional information available at www.pmc.umicore.com

象形图

Health hazardExclamation mark

警示用语:

Danger

危险声明

危险分类

Aquatic Chronic 3 - Carc. 1B Inhalation - Skin Sens. 1

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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