561487
噻霉酮
97%
别名:
1,2-苯并异噻唑-3-酮, 1,2-苯并异噻唑酮, 2,3-二氢-1,2-苯并噻唑-3-酮, 3-羟基-1,2-苯并异噻唑, 苯并异噻唑啉-3-酮
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关于此项目
经验公式（希尔记法）:
C7H5NOS
化学文摘社编号:
分子量:
151.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-120-9
MDL number:
Assay:
97%
Form:
solid
InChI key
DMSMPAJRVJJAGA-UHFFFAOYSA-N
InChI
1S/C7H5NOS/c9-7-5-3-1-2-4-6(5)10-8-7/h1-4H,(H,8,9)
SMILES string
Oc1nsc2ccccc12
assay
97%
form
solid
mp
154-158 °C (lit.)
Quality Level
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General description
1,2-苯并异噻唑3（2H）-酮可以通过使2-巯基苯甲酸与二苯基磷酰基叠氮化物反应来合成。
Application
1,2-苯并异噻唑-3(2H)-酮可作为前体合成生物活性更高的1,2-苯并异噻唑啉-3-酮(BIT)。
Disclaimer
本品不可用作全球生物杀灭剂法规监管的生物杀灭剂，包括但不限于：美国联邦杀虫剂、杀菌剂和灭鼠剂法(US EPA′s Federal Insecticide Fungicide and Rodenticide Act)、欧盟生物杀灭剂法规(European Biocidal Products Regulation)、加拿大虫害管理监管机构(Canada’s Pest Management Regulatory Agency)、土耳其生物杀灭剂法规(Turkey’s Biocidal Products Regulation)、韩国生物杀灭剂法(Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR))等。
signalword
Danger
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
法规信息
农药列管产品
此项目有
Convenient Synthesis of 1, 2-Benzisothiazol-3 (2H)-ones by Cyclization Reaction
of Acyl Azide
of Acyl Azide
Chiyoda T, et al.
Synlett, 2000(10), 1427-1428 (2000)
Tomasz Sławik et al.
Journal of chromatography. A, 952(1-2), 295-299 (2002-06-18)
The lipophilicity (R(Mo)) and specific hydrophobic surface area of seven 1,2-benzisothiazol-3(2H)-ones have been determined by reversed-phase TLC and the effect of different mobile-phase modifiers (acetone, acetonitrile, methanol) on the retention has been studied. The linear correlations between the volume fraction
Occupational hand dermatitis due to 1,2-benzisothiazolin-3-one in the water-softener manufacturing industry.
S M Cooper et al.
Contact dermatitis, 40(4), 221-221 (1999-04-20)
D L Greenway et al.
Letters in applied microbiology, 29(5), 298-302 (2000-02-09)
The effect of a commonly used biocide, 1,2-benzisothiazolin-3-one (BIT) on ppGpp accumulation in the pathogen, Pseudomonas aeruginosa PAO1, and an environmental isolate, Ps. fluorescens, was examined. It is concluded that BIT is able to induce a stringent response in Ps.
Mateo Alajarin et al.
The Journal of organic chemistry, 75(11), 3737-3750 (2010-05-14)
Under thermal activation in solution, N-[2-(1,3-oxathiolan-2-yl)]phenyl ketenimines and carbodiimides were converted into 2,1-benzisothiazol-3-ones bearing a pendant N-styryl or imidoyl fragment, respectively. These processes should occur with the concomitant formation of ethylene as result of the fragmentation of the 1,3-oxathiolane ring.
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