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Merck
CN

101621

3-Chloro-2-methylaniline

99%

Synonym(s):

2-Amino-6-chlorotoluene, 3-Chloro-o-toluidine

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About This Item

Linear Formula:
ClC6H3(CH3)NH2
CAS Number:
87-60-5
Molecular Weight:
141.60
Beilstein:
471697
EC Number:
201-756-6
MDL number:
MFCD00007766
UNSPSC Code:
12352100
PubChem Substance ID:
24846547
NACRES:
NA.22

Key Documents

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Quality Level

100

Assay

99%

refractive index

n20/D 1.588 (lit.)

bp

115-117 °C/10 mmHg (lit.)

mp

2 °C (lit.)

density

1.185 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

Cc1c(N)cccc1Cl

InChI

1S/C7H8ClN/c1-5-6(8)3-2-4-7(5)9/h2-4H,9H2,1H3

InChI key

ZUVPLKVDZNDZCM-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Statements

H302,H314,H334

Hazard Classifications

Acute Tox. 4 Oral - Resp. Sens. 1 - Skin Corr. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCL9763
BCCM4815
BCCB5810
BCBW0982
BCBS9933

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K Fuchs et al.
Journal of general microbiology, 137(8), 2033-2039 (1991-08-01)
Rhodococcus rhodochrous strain CTM co-metabolized 2-methylaniline and some of its chlorinated isomers in the presence of ethanol as additional carbon source. Degradation of 2-methylaniline proceeded via 3-methylcatechol, which was metabolized mainly by meta-cleavage. In the case of 3-chloro-2-methylaniline, however, only
Nada S Abdelwahab et al.
Journal of chromatographic science, 53(4), 484-491 (2014-07-14)
Two accurate, selective and precise chromatographic methods, namely thin-layer chromatography (TLC)-densitometric method and reversed phase high-performance liquid chromatography (RP-HPLC) method, were developed and validated for the simultaneous determination of tolfenamic acid (TOL) and its two major impurities, 2-chlorobenzoic acid (CBA)

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