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101893

Perfluorobenzophenone

Name: Perfluorobenzophenone
Brand: ALDRICH

98%

Synonym(s):

Decafluorobenzophenone, Perfluorobenzophenone

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About This Item

Linear Formula:

C₆F₅COC₆F₅

CAS Number:

853-39-4

Molecular Weight:

362.12

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24846557

EC Number:

212-717-8

Beilstein/REAXYS Number:

2066476

MDL number:

MFCD00000295

Assay:

98%

Form:

solid

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Properties

Quality Level

100

assay

98%

form

solid

mp

90-95 °C (lit.)

SMILES string

Fc1c(F)c(F)c(c(F)c1F)C(=O)c2c(F)c(F)c(F)c(F)c2F

InChI

1S/C13F10O/c14-3-1(4(15)8(19)11(22)7(3)18)13(24)2-5(16)9(20)12(23)10(21)6(2)17

InChI key

WWQLXRAKBJVNCC-UHFFFAOYSA-N

Description

Application

Perfluorobenzophenone was used in the synthesis of fluorinated acridones and acridines.

Biochem/physiol Actions

Perfluorobenzophenone alcoholic solution generates ketyl and radical anion which can be studied by electron spin resonance spectra. Perfluorobenzophenone undergoes photolysis to form ketyl (C₆F₅⁾C^.OH radical.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Orthogonal Synthesis of Fluorinated Acridones and Acridines from Perfluorobenzophenone.

Del Buttero P, et al

European Journal of Organic Chemistry, 2011(12), 2265-2271 (2011)

The Electron Spin Resonance Spectra of the Photochemically Produced Perfluorobenzophenone Ketyl and Anion Radicals.

Sargent FP and Bailey MG.

Canadian Journal of Chemistry, 49(13), 2350-2352 (1971)

The Photochemically Produced Ketyl of Perfluorobenzophenone: Electron Spin Resonance Studies of Solvent Effects.