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Merck
CN

107247

Diethyl sulfide

98%

Synonym(s):

1,1′-Thiobisethane, Ethyl sulfide, NSC 75157

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About This Item

Linear Formula:
(C2H5)2S
CAS Number:
352-93-2
Molecular Weight:
90.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24846758
EC Number:
206-526-9
Beilstein/REAXYS Number:
1696909
MDL number:
MFCD00009270

Key Documents

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Product Name

Diethyl sulfide, 98%

InChI key

LJSQFQKUNVCTIA-UHFFFAOYSA-N

InChI

1S/C4H10S/c1-3-5-4-2/h3-4H2,1-2H3

SMILES string

CCSCC

vapor pressure

105 mmHg ( 37.7 °C)

assay

98%

refractive index

n20/D 1.442 (lit.)

bp

90-92 °C (lit.)

mp

−100 °C (lit.)

solubility

H2O: insoluble
alcohol: miscible
diethyl ether: miscible

density

0.837 g/mL at 25 °C (lit.)

functional group

thioether

Quality Level

200

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Application

Diethyl sulfide was used to assess the quantification procedure for nine volatile sulfur compounds in complex gaseous samples by solid-phase microextraction.

General description

Diethyl sulfide forms 1:1 charge transfer complex with iodine. It undergoes photocatalytic degradation over TiO2 . It is commonly used as solvent for anhydrous mineral salts and in plating baths for coating metals with gold or silver.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

15.8 °F - closed cup

flash_point_c

-9 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
SDBB5866
STBL4087
STBK6316
STBJ8130
STBJ2925

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Molecular Complexes and Their Spectra. XIII. Complexes of Iodine with Amides, Diethyl Sulfide and Diethyl Disulfide.
Tsubomura H and Lang RP.
Journal of the American Chemical Society, 83(9), 2085-2092 (1961)
Photocatalytic destruction of gaseous diethyl sulfide over TiO2.
Vorontsov AV, et al.
Applied Catalysis. B, Environmental, 32(1), 11-24 (2001)
Femtochemistry uncovers the nature of electron transfer reactions.
A W Castleman et al.
Proceedings of the National Academy of Sciences of the United States of America, 96(8), 4219-4220 (1999-04-14)
Andrea Belancic Majcenovic et al.
Journal of agricultural and food chemistry, 50(23), 6653-6658 (2002-10-31)
Ethanethiol and diethyl disulfide (DEDS) most often occurred at levels above their olfactive threshold in wines with nauseous sulfur-linked smells. As ethanethiol is very oxidizable and chemically reactive, a stable isotopic dilution analysis of both ethanethiol and its disulfide in
V Vodyanoy et al.
Neuroscience letters, 73(3), 253-258 (1987-01-27)
The steady-state conductance of planar bimolecular lipid membranes (BLMs) modified with rat olfactory epithelial homogenate (ROH) becomes sensitive to very low concentrations of odorant in the presence of adenosine triphosphate (ATP) and guanosine triphosphate (GTP). The chemosensitivity is not observed
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