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Vinyl laurate

Name: Vinyl laurate
Brand: ALDRICH

Wacker Chemie AG, ≥98% (GC)

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About This Item

Linear Formula:

CH₃(CH₂)₁₀COOCH=CH₂

CAS Number:

2146-71-6

Molecular Weight:

226.36

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57646832

EC Number:

218-414-7

Beilstein/REAXYS Number:

1778369

MDL number:

MFCD00048421

Assay:

≥98% (GC)

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Properties

Quality Level

100

assay

≥98% (GC)

manufacturer/tradename

Wacker Chemie AG

bp

254 °C/1013 hPa (lit.)

solubility

H₂O: slightly soluble 1 g/L at 20 °C

density

0.871 g/mL at 20 °C (lit.)

functional group

ester

SMILES string

CCCCCCCCCCCC(=O)OC=C

InChI

1S/C14H26O2/c1-3-5-6-7-8-9-10-11-12-13-14(15)16-4-2/h4H,2-3,5-13H2,1H3

InChI key

GLVVKKSPKXTQRB-UHFFFAOYSA-N

Description

General description

Vinyl laurate is a clear, colorless to light yellow colored liquid. The flash point is 125°C. It forms aqueous colloidal microgel by copolymerization with N-isopropylacrylamide. The enzymatic acylation of Avicel cellulose with vinyl laurate, a solvent free reaction system, was studied.

Application

Vinyl laurate was used in the synthesis of laurate and stearate esters of corn starch. It was used as the acyl donor during synthesis of sucrose laurate esters catalyzed by Bacillus pseudofirmus AL-89 . Vinyl laurate was also used in the preparation of chirally deuterated benzyl chlorides.

Other Notes

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Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

257.0 °F

flash_point_c

125 °C

ppe

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Synthesis of sucrose laurate using a new alkaline protease.

Pedersen NR, et al.

Tetrahedron Asymmetry, 14(6), 667-673 (2003)

Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants.

Junistia L, et al.

Starch/Staerke, 60(12), 667-675 (2008)

Chirally deuterated benzyl chlorides from benzyl alcohols via hexachloroacetone/polymer-supported triphenylphosphine: synthesis of protected (2S, 3S)-[3-(2)H, (15)N]-tyrosine.

Derek W Barnett et al.

Journal of labelled compounds & radiopharmaceuticals, 56(1), 6-11 (2013-11-29)

Chirally deuterated benzyl chlorides were prepared using novel, general hexachloroacetone/polymer-supported triphenylphosphine treatment of chirally deuterated benzyl alcohols. Doubly labeled protected tyrosine was obtained in 62% yield with 86% de at the α-carbon and 82% de at the β-carbon. Key in

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Global Trade Item Number

SKU	GTIN
277576-2KG	04061837769054
277576-4X100G	04061837769078
207888-100G	04061838769114
V800086-250ML	04061838229908
470864-50G	04061832359458
1019480250	04022536026749
V800086-6X250ML	04061838157898
16050-500ML	04061838151315