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10914

Isopropenyl acetate

Name: Isopropenyl acetate
Brand: ALDRICH

Wacker Chemie AG, ≥99.0% (GC)

Synonym(s):

IPA, 1-Methylvinyl acetate

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About This Item

Linear Formula:

CH₃CO₂C(CH₃)=CH₂

CAS Number:

108-22-5

Molecular Weight:

100.12

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57646850

EC Number:

203-562-7

Beilstein/REAXYS Number:

1280347

MDL number:

MFCD00008709

Assay:

≥99.0% (GC)

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Properties

Quality Level

200

assay

≥99.0% (GC)

manufacturer/tradename

Wacker Chemie AG

refractive index

n20/D 1.401 (lit.)

bp

94 °C (lit.)

density

0.922 g/mL at 20 °C, 0.909 g/mL at 25 °C (lit.)

SMILES string

CC(=C)OC(C)=O

InChI

1S/C5H8O2/c1-4(2)7-5(3)6/h1H2,2-3H3

InChI key

HETCEOQFVDFGSY-UHFFFAOYSA-N

Description

General description

Isopropenyl acetate is a superior acetylating agent and decomposes into ketene and acetone by heating in presence of acid catalysts. Iodine in isopropenyl acetate is a unique catalyst for the acetylation of a variety of alcohols, phenols and amines under solvent free conditions.

Other Notes

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pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H335

pcodes

P210 - P233 - P240 - P241 - P242 - P243

Hazard Classifications

Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

66.2 °F - closed cup

flash_point_c

19 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品

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Reactions of isopropenyl acetate.

Hagemeyer HJ and Hull DC.

Ind. and Eng. Chem., 41(12), 2920-2924 (1949)

Molecular iodine in isopropenyl acetate (IPA): a highly efficient catalyst for the acetylation of alcohols, amines and phenols under solvent free conditions.

Ahmed N and van Lier JE.

Tetrahedron Letters, 47(30), 5345-5349 (2006)

Global Trade Item Number

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