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Merck
CN

109576

1,1′-Dimethylferrocene

95%, solid

Synonym(s):

Bis(methylcyclopentadienyl)iron

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About This Item

Empirical Formula (Hill Notation):
C12H14Fe
CAS Number:
Molecular Weight:
214.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-067-3
MDL number:
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Product Name

1,1′-Dimethylferrocene, 95%

InChI key

GJFIEPAJMYPAGC-UHFFFAOYSA-N

InChI

1S/2C6H7.Fe/c2*1-6-4-2-3-5-6;/h2*2-5H,1H3;

SMILES string

[Fe].C[C]1[CH][CH][CH][CH]1.C[C]2[CH][CH][CH][CH]2

assay

95%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

37-40 °C (lit.)

Quality Level

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

226.4 °F - closed cup

flash_point_c

108.00 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)


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J H Luong et al.
Journal of molecular recognition : JMR, 8(1-2), 132-138 (1995-01-01)
Inclusion complexes of 1,1'-dimethylferrocene (DMFe) with alpha-, 2-hydroxypropyl-beta- or gamma-cyclodextrins were formed in aqueous systems. For the first time, the interacting DMFe-cyclodextrin systems have been characterized using cyclic voltammetry which enabled the estimation of the complexation order, the formation constant
P C Pandey et al.
Analytical biochemistry, 252(1), 136-142 (1997-11-05)
This article describes the research investigations on the development of the amperometric biosensors based on mediated bioelectrochemistry. The mediated bioelectrochemistry involving horseradish peroxidase and glucose oxidase within the graphite paste is reported. The enzyme horseradish peroxidase together with electrochemical mediator
D J Claremont et al.
Diabetologia, 29(11), 817-821 (1986-11-01)
Miniature, amperometric glucose sensors were constructed using entrapped 1,1'-dimethylferrocene to mediate electron transfer between immobilised glucose oxidase and a carbon base electrode. Electrodes were calibrated in buffered glucose solutions and then implanted in the subcutaneous tissue of anaesthetised, non-diabetic pigs.
K B Male et al.
Applied biochemistry and biotechnology, 44(1), 91-100 (1994-01-01)
Water-soluble 2-hydroxypropyl-beta-cyclodextrin (Hp-beta-CyD), a cyclic and nonreducing oligosaccharide was used to enclose a hydrophobic guest molecule 1,1'-dimethylferrocene (DMF) to form a water-soluble yellow complex. At high concentrations (300 mM), Hp-beta-CyD enclosed up to 100 mM DMF. The yellow complex was
M Wenzel et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 43(11-12), 963-966 (1988-11-01)
The relative stabilities of different ferricinium cations were studied in buffer or serum-containing solution and in vivo and compared with their cytostatic effects in cultures of Yoshida ascites tumor cells. Although the ferricinium cation itself was the most unstable cation

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