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Merck
CN

117609

Cyclopentadienylmolybdenum(II) tricarbonyl, dimer

98%

Synonym(s):

Cyclopentadienyltricarbonylmolybdenum dimer, Hexacarbonylbis(η5 -cyclopentadienyl)dimolybdenum(I), Hexacarbonylbis(cyclopentadienyl)dimolybdenum

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About This Item

Empirical Formula (Hill Notation):
C16H10Mo2O6
CAS Number:
Molecular Weight:
490.13
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
235-156-0
MDL number:
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Product Name

Cyclopentadienylmolybdenum(II) tricarbonyl, dimer, 98%

InChI key

XCUPBPUEWLTPMQ-UHFFFAOYSA-N

InChI

1S/2C5H5.6CO.2Mo/c2*1-2-4-5-3-1;6*1-2;;/h2*1-5H;;;;;;;;

SMILES string

[Mo][Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

assay

98%

form

solid

reaction suitability

core: molybdenum
reagent type: catalyst

mp

222 °C (dec.) (lit.)

Quality Level

Application

  • Group 6 Carbonyl Complexes of N, O, P-ligands: Reviews the use of cyclopentadienyl molybdenum(II) dicarbonyl and tricarbonyl complexes as precursors for catalysts in olefin epoxidation. (SM Bruno, AA Valente, IS Gonçalves, 2023).
  • Monitoring Equilibrium Reaction Dynamics of a Nearly Barrierless Molecular Rotor: Describes using cyclopentadienylmolybdenum tricarbonyl dimer in ultrafast vibrational echo experiments to observe dynamic processes in barrierless molecular rotors. (IA Nilsen, DG Osborne, AM White, JM Anna, 2014).

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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