120162
3,5-Dibromopyridine
≥98.0%
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About This Item
Empirical Formula (Hill Notation):
C5H3Br2N
CAS Number:
Molecular Weight:
236.89
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-916-4
Beilstein/REAXYS Number:
108477
MDL number:
Assay:
≥98.0%
Form:
solid
Product Name
3,5-Dibromopyridine, ≥98.0%
form
solid
InChI key
SOSPMXMEOFGPIM-UHFFFAOYSA-N
InChI
1S/C5H3Br2N/c6-4-1-5(7)3-8-2-4/h1-3H
SMILES string
Brc1cncc(Br)c1
assay
≥98.0%
mp
110-115 °C (lit.)
functional group
bromo
Quality Level
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Application
3,5-Dibromopyridine was used in the synthesis of new Hg(II) complexes with halogen (chloro, bromo, iodo) and 3,5-disubstituted pyridine ligands.
General description
3,5-Dibromopyridine undergoes lithiation with lithium diisopropylamide and on subsequent reaction with electrophiles yields 4-alkyl-3,5-dibromopyridines.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis of 4-alkyl-3, 5-dibromo-, 3-bromo-4, 5-dialkyl-and 3, 4, 5-trialkylpyridines via sequential metalation and metal-halogen exchange of 3, 5-dibromopyridine.
Gu YG and Bayburt EK.
Tetrahedron Letters, 37(15), 2565-2568 (1996)
Pyridine complexes of mercury (II) halides: Implications of a soft metal center for crystal engineering.
Hu C, et al.
CrystEngComm, 9(7), 603-610 (2007)
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