120421
2-(Ethylthio)ethylamine hydrochloride
98%
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About This Item
Linear Formula:
C2H5SCH2CH2NH2 · HCl
CAS Number:
Molecular Weight:
141.66
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
259-081-8
MDL number:
Assay:
98%
Product Name
2-(Ethylthio)ethylamine hydrochloride, 98%
InChI key
AZQOTRRSHMSXFJ-UHFFFAOYSA-N
InChI
1S/C4H11NS.ClH/c1-2-6-4-3-5;/h2-5H2,1H3;1H
SMILES string
Cl.CCSCCN
assay
98%
mp
144-146 °C (lit.)
functional group
amine
thioether
Application
2-(Ethylthio)ethylamine hydrochloride was used in the preparation of (syn, syn)-2,7-Bis(N-2-ethylthioethylmethylimino)-1,8-naphthyridine. It was used in the synthesis of N-functionalized bis(phosphino)amine ligands with ether, thioether and pyridyl ethers.
General description
2-(Ethylthio)ethylamine forms complexes with Pd(II) and Pt(II).
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Pd (II) and Pt (II) complexes with 2-(ethylthio) ethylamine. Crystal structure of [Pd (2-(ethylthio) ethylamine) Cl2] and [Pd (2-(ethylthio) ethylamine)2](ClO4)2.
Riera X, et al.
Polyhedron, 18(1), 65-73 (1998)
Elaboration of 1, 8-naphthyridine-2, 7-dicarboxaldehyde into novel 2, 7-dimethylimine derivatives.
Vu C, et al.
Journal of Heterocyclic Chemistry, 39(4), 829-832 (2002)
Zhiqiang Weng et al.
Dalton transactions (Cambridge, England : 2003), (32)(32), 3493-3498 (2007-08-08)
Several N-functionalized bis(phosphino)amine ligands with ether, thioether and pyridyl tethers [(R'')2PN(R')P(R'')2=PNP] () have been synthesized. They react with CrCl3(THF)3 in CH2Cl2 to give dinuclear chloro bridged Cr2(micro-Cl)2Cl4(PNP)2 () which converts to the corresponding mononuclear solvento complexes fac-CrCl3(PNP)(NCR) (). The structures
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