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122831

2-Aminobenzyl alcohol

98%

Synonym(s):

2-(Hydroxymethyl)aniline

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About This Item

Linear Formula:
H2NC6H4CH2OH
CAS Number:
5344-90-1
Molecular Weight:
123.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24847510
EC Number:
226-293-7
Beilstein/REAXYS Number:
1072211
MDL number:
MFCD00007749
Assay:
98%
Form:
solid
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Quality Segment

assay

98%

form

solid

bp

162 °C/15 mmHg (lit.)

mp

81-83 °C (lit.)

functional group

hydroxyl

SMILES string

Nc1ccccc1CO

InChI

1S/C7H9NO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5,8H2

InChI key

VYFOAVADNIHPTR-UHFFFAOYSA-N

General description

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde.

Application

2-Aminobenzyl alcohol was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

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Storage Class

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Gloves

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