122858
2-Amino-5-bromopyridine
97%
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About This Item
Empirical Formula (Hill Notation):
C5H5BrN2
CAS Number:
Molecular Weight:
173.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-019-9
Beilstein/REAXYS Number:
108737
MDL number:
Assay:
97%
Form:
solid
Quality Level
assay
97%
form
solid
mp
133-138 °C (lit.)
functional group
bromo
SMILES string
Nc1ccc(Br)cn1
InChI
1S/C5H5BrN2/c6-4-1-2-5(7)8-3-4/h1-3H,(H2,7,8)
InChI key
WGOLHUGPTDEKCF-UHFFFAOYSA-N
General description
2-Amino-5-bromopyridine is a brominated aromatic amine reagent and is used for labeling of model reducing-end oligosaccharides via reductive amination.
Application
2-Amino-5-bromopyridine has been used to study the hydrogen-bonding patterns in the 2-amino-5-bromopyridine benzoic acid (1/1) cocrystal. It has been used in the synthesis of 2-amino-5-bromopyridinium 3-aminobenzoate salt and polycyclic azaarenes.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Tetrahedron Letters, 48, 5039-5039 (2007)
Min Li et al.
Rapid communications in mass spectrometry : RCM, 17(13), 1462-1466 (2003-06-24)
Model reducing-end oligosaccharides were successfully labeled by a brominated aromatic amine reagent, 2-amino-5-bromopyridine (ABP), through reductive amination. Using either a combination of liquid chromatography/electrospray ionization mass spectrometry (LC/ESI-MS) with in-source fragmentation or liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS), sequence
Madhukar Hemamalini et al.
Acta crystallographica. Section E, Structure reports online, 66(Pt 3), o663-o663 (2010-01-01)
In the title adduct, C(5)H(5)BrN(2)·C(7)H(6)O(2), the carboxyl group of the benzoic acid mol-ecule is twisted away from the attached ring by 12.97 (11)°. The 2-amino-5-bromo-pyridine mol-ecules inter-act with the carboxylic group of neighbouring benzoic acid mol-ecules through N-H⋯O and O-H⋯N hydrogen
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 122858-5G | 04061838721853 |
| 122858-25G | 04061838721846 |