124109
1-Bromo-2-methylnaphthalene
technical grade, 90%
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About This Item
Linear Formula:
CH3C10H6Br
CAS Number:
Molecular Weight:
221.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-966-1
Beilstein/REAXYS Number:
2042531
MDL number:
Assay:
90%
Form:
liquid
InChI key
CMIMBQIBIZZZHQ-UHFFFAOYSA-N
InChI
1S/C11H9Br/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,1H3
SMILES string
Cc1ccc2ccccc2c1Br
grade
technical grade
assay
90%
form
liquid
Quality Level
bp
296 °C (lit.)
density
1.418 g/mL at 25 °C (lit.)
functional group
bromo
Related Categories
General description
Dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngml-1 levels. It undergoes asymmetric cross-coupling reaction with its corresponding Grignard reagent using a nickel catalyst to form non-racemic 2,2′-dimethyl-1,1′-binaphthyl.
Application
1-Bromo-2-methylnaphthalene was used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Determination of halogenated compounds with supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
Olson LK and Caruso JA.
Journal of Analytical Atomic Spectrometry, 7(6), 993-998 (1992)
Synthesis of chiral binaphthalenes using the asymmetric Suzuki reaction.
Cammidge AN and Crepy KVL.
Tetrahedron, 60(20), 4377-4386 (2004)
N A Vinokurova
Voprosy onkologii, 21(3), 19-24 (1975-01-01)
The author presents an analysis of the results of the combination chemotherapy with natulan, vincristin, novembichine and prednisolone in 43 patients showing generalized lymphogranulomatosis, mainly with recurrences following radiation and chemotherapy with different antitumor substances. The results of the combination
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