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Merck
CN

124109

1-Bromo-2-methylnaphthalene

technical grade, 90%

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About This Item

Linear Formula:
CH3C10H6Br
CAS Number:
2586-62-1
Molecular Weight:
221.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24847598
EC Number:
219-966-1
Beilstein/REAXYS Number:
2042531
MDL number:
MFCD00003871
Assay:
90%
Form:
liquid

Key Documents

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Product Name

1-Bromo-2-methylnaphthalene, technical grade, 90%

InChI key

CMIMBQIBIZZZHQ-UHFFFAOYSA-N

InChI

1S/C11H9Br/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,1H3

SMILES string

Cc1ccc2ccccc2c1Br

grade

technical grade

assay

90%

form

liquid

refractive index

n20/D 1.648 (lit.)

bp

296 °C (lit.)

density

1.418 g/mL at 25 °C (lit.)

functional group

bromo

Quality Level

100

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Application

1-Bromo-2-methylnaphthalene was used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry.

General description

Dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngml-1 levels. It undergoes asymmetric cross-coupling reaction with its corresponding Grignard reagent using a nickel catalyst to form non-racemic 2,2′-dimethyl-1,1′-binaphthyl.

signalword

Warning

pictograms

Exclamation mark
GHS07

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
STBH4603
STBF2960V
S20073
08016HD
05421DD

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Determination of halogenated compounds with supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
Olson LK and Caruso JA.
Journal of Analytical Atomic Spectrometry, 7(6), 993-998 (1992)
Synthesis of chiral binaphthalenes using the asymmetric Suzuki reaction.
Cammidge AN and Crepy KVL.
Tetrahedron, 60(20), 4377-4386 (2004)
N A Vinokurova
Voprosy onkologii, 21(3), 19-24 (1975-01-01)
The author presents an analysis of the results of the combination chemotherapy with natulan, vincristin, novembichine and prednisolone in 43 patients showing generalized lymphogranulomatosis, mainly with recurrences following radiation and chemotherapy with different antitumor substances. The results of the combination

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