124133
3-Bromoquinoline
98%
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About This Item
Empirical Formula (Hill Notation):
C9H6BrN
CAS Number:
Molecular Weight:
208.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-237-1
Beilstein/REAXYS Number:
112939
MDL number:
Product Name
3-Bromoquinoline, 98%
InChI key
ZGIKWINFUGEQEO-UHFFFAOYSA-N
InChI
1S/C9H6BrN/c10-8-5-7-3-1-2-4-9(7)11-6-8/h1-6H
SMILES string
Brc1cnc2ccccc2c1
assay
98%
form
liquid
refractive index
n20/D 1.664 (lit.)
bp
274-276 °C (lit.)
mp
13-15 °C (lit.)
density
1.533 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
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General description
3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Tributylmagnesium ate complex-mediated bromine-magnesium exchange of bromoquinolines: a convenient access to functionalized quinolines.
Dumouchel S, et al.
Tetrahedron Letters, 44(10), 2033-2035 (2003)
Alexander V Shaferov et al.
Sensors (Basel, Switzerland), 20(11) (2020-06-11)
Pd(0)-catalyzed amination was employed for the synthesis of a new family of (S)-1,1'-bianaphthalene-2,2'-diamine derivatives possessing additional chiral and fluorophore substituents. The compounds thus obtained were tested as potential detectors of seven amino alcohols, and some of them were found to
Bin Yang et al.
Environmental science and pollution research international, 23(4), 3399-3405 (2015-10-23)
The solubilities of 19 different kinds of N-heteroaromatic compounds in aqueous solutions with different concentrations of NaCl were determined at 298.15 K with a UV-vis spectrophotometry and titration method, respectively. Setschenow constants, Ks, were employed to describe the solubility behavior
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