135615
2-Bromo-2-methylpropane
98%
Synonym(s):
2-methyl-2-bromopropane, tert-Butyl bromide
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About This Item
Linear Formula:
(CH3)3CBr
CAS Number:
Molecular Weight:
137.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-065-9
Beilstein/REAXYS Number:
1730892
MDL number:
Assay:
98%
Form:
liquid
Quality Level
assay
98%
form
liquid
contains
0.5% potassium carbonate as stabilizer
refractive index
n20/D 1.4279 (lit.)
bp
71-73 °C (lit.)
mp
−20 °C (lit.)
solubility
H2O: insoluble, organic solvents: miscible
density
1.22 g/mL at 20 °C (lit.)
functional group
alkyl halide, bromo
SMILES string
CC(C)(C)Br
InChI
1S/C4H9Br/c1-4(2,3)5/h1-3H3
InChI key
RKSOPLXZQNSWAS-UHFFFAOYSA-N
General description
2-Bromo-2-methylpropane (tert-Butyl bromide) is a versatile reactant in organic synthesis, facilitating the introduction of the tert-butyl group. It causes the massive deguanylation of guanine based-nucleosides and massive deadenylation of adenine based-nucleosides.
Application
2-Bromo-2-methylpropane was used to study the massive deadenylation of adenine based-nucleosides induced by halogenated alkanes under physiological conditions.
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signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Deguanylation of guanine based-nucleosides and calf thymus DNA induced by halogenated alkanes at the physiological condition.
Sherchan J and Lee E-S.
Bull. Korean Chem. Soc., 30(12), 2318-2328 (2009)
tert-Butyl Bromide-Promoted Intramolecular Cyclization of 2-Arylamino Phenyl Ketones and Its Combination with Cu-Catalyzed C-N Coupling: Synthesis of Acridines at Room Temperature
Z Cao, et al.
The Journal of Organic Chemistry, 85, 10167-10174 (2020)
Deadenylation of Adenine Based-Nucleosides and Calf thymus DNA Induced by Halogenated Alkanes at the Physiological Condition.
Sherchan J, et al.
Bull. Korean Chem. Soc., 30(10), 2318-2328 (2009)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 135615-500G | 04061837586613 |
| 135615-100G | 04061838730756 |
| 135615-5G | 04061838730763 |