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Merck
CN

135879

Sulfur trioxide trimethylamine complex

Synonym(s):

NSC 9838, Trimethylamine sulfur trioxide complex

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About This Item

Linear Formula:
(CH3)3N · SO3
CAS Number:
Molecular Weight:
139.17
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-614-7
Beilstein/REAXYS Number:
3681759
MDL number:
Form:
solid
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form

solid

Quality Level

reaction suitability

reagent type: oxidant

mp

232 °C (dec.) (lit.)

functional group

amine

SMILES string

CN(C)C.O=S(=O)=O

InChI

1S/C3H9N.O3S/c2*1-4(2)3/h1-3H3;

InChI key

DXASQZJWWGZNSF-UHFFFAOYSA-N

Application

Reactant for sulfation reactions involving:
  • Synthesis of sulfate-conjugated resveratrol metabolites
  • Chitooligosaccharides used for anti-HIV-1 activity
  • Dodecyl thioglycopyranoside used as a surfactant for enantiomeric separation
  • Glycosaminoglycans which facilitate activation of signaling pathways dependent on sulfation pattern
  • Polysaccharides as heparan sulfate mimetics

Nucleophile for the synthesis of α-tosyloxy ketones


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Jure Acimovic et al.
PloS one, 8(7), e68031-e68031 (2013-07-12)
24S- and 27-hydroxycholesterol (24OHC and 27OHC) are potent regulators of different biochemical systems in vitro and are the major circulating oxysterols. A small fraction of these oxysterols has been reported to be sulphated but there are no detailed studies. We
Juliane Strätz et al.
Macromolecular bioscience, 20(2), e1900403-e1900403 (2019-12-31)
Sulfated cellulose (CS) represents an interesting biopolymer due to bioactivity comparable to heparin. However, use of CS for making surface coatings or hydrogels requires the presence of reactive groups for covalent reactions. Here, an approach is presented to oxidize cellulose
Shuqian Hu et al.
Carbohydrate polymers, 236, 116052-116052 (2020-03-17)
In this study, a series water soluble sulfate polysaccharides (SPS) with different degrees of substitutions (DS = 0.02∼0.28) were prepared using a linear water-insoluble β-d-(1→3)-glucan. SPS-1, SPS-3 and SPS-7 with substitution degrees of 0.02, 0.06 and 0.25 were used as templates to



Global Trade Item Number

SKUGTIN
F0750-25G04061832342825
135879-5G04061833498644
135879-100G04061838730985
135879-500G04061833544495