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137995

1,2,3-Trimethoxybenzene

Name: 1,2,3-Trimethoxybenzene
Brand: ALDRICH

98%

Synonym(s):

Pyrogallol trimethyl ether

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About This Item

Linear Formula:

C₆H₃(OCH₃)₃

CAS Number:

634-36-6

Molecular Weight:

168.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848225

EC Number:

211-207-2

Beilstein/REAXYS Number:

1910422

MDL number:

MFCD00008358

Assay:

98%

Form:

chunks

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Properties

Quality Level

100

assay

98%

form

chunks

bp

241 °C (lit.)

mp

43-47 °C (lit.)

density

1.112 g/mL at 25 °C (lit.)

SMILES string

COc1cccc(OC)c1OC

InChI

1S/C9H12O3/c1-10-7-5-4-6-8(11-2)9(7)12-3/h4-6H,1-3H3

InChI key

CRUILBNAQILVHZ-UHFFFAOYSA-N

Description

General description

1,2,3-Trimethoxybenzene on condensation with 2,4-diamino-5-(hydroxymethyl)pyrimidine yields 2,4-diamino-5-(2,3,4-trimethoxybenzyl)pyrimidine.

Application

1,2,3-Trimethoxybenzene was used to study the effect of solvent on photoinduced electron-transfer reactions.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

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Synthesis of cyclophanetetrayne complexes from bis(propargyldicobalt) dication equivalents.

Romelo Gibe et al.

Chemical communications (Cambridge, England), (14)(14), 1550-1551 (2002-08-23)

Nicholas reactions of the p-phenyl linked bis(propargyl acetate) complex (3a) with electron rich arenes give cyclophanetetrayne complexes (5). The use of bis(propargyl ether) complex (8) with (3a) allows formation of a mixed cyclophanetetrayne complex (9), and in addition gives retro-Nicholas/intramolecular

An Au-catalyzed cyclialkylation of electron-rich arenes with epoxides to prepare 3-chromanols.

Zhangjie Shi et al.

Journal of the American Chemical Society, 126(19), 5964-5965 (2004-05-13)

A gold-catalyzed cyclialkylation of electron-rich arenes with tethered epoxides afforded 3-chromanols stereospecifically.

An isotropic chemical shift-chemical shift anisotropic correlation experiment using discrete magic angle turning.

Jian Zhi Hu et al.

Journal of magnetic resonance (San Diego, Calif. : 1997), 198(1), 105-110 (2009-02-28)

An isotropic-anisotropic shift 2D correlation spectroscopy is introduced that combines the advantages of both magic angle turning (MAT) and magic angle hopping (MAH) technologies. In this new approach, denoted DMAT for "discrete magic angle turning", the sample rotates clockwise followed

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Global Trade Item Number

SKU	GTIN
137995-100G	04061838345943
137995-25G	04061838732163