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Merck
CN

14446

Biphenyl sodium complex solution

technical, 0.7 M±0.2 M in diethylene glycol diethyl ether

Synonym(s):

Sodium biphenyl complex

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About This Item

Linear Formula:
C6H5C6H5 · Na
CAS Number:
5137-46-2
Molecular Weight:
177.20
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
57647157
MDL number:
MFCD00013182
Beilstein/REAXYS Number:
3989646
Form:
liquid

Key Documents

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InChI

1S/C12H9.Na/c1-3-7-11(8-4-1)12-9-5-2-6-10-12;/h1,3-10H;

SMILES string

[Na]c1ccc(cc1)-c2ccccc2

InChI key

UUNVZHGYJSUMDC-UHFFFAOYSA-N

grade

technical

form

liquid

shelf life

limited shelf life

reaction suitability

reagent type: reductant

packaging

pk of 20 × 15 mL

concentration

0.7 M±0.2 M in diethylene glycol diethyl ether

density

1,100  g/cm3

functional group

phenyl

storage temp.

2-8°C

Quality Level

100

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Related Categories

General description

Biphenyl sodium complex solution is mainly favorable to the reduction of organic halogen compounds and is commonly used as a defluorination reagent in organic synthesis.

Other Notes

Reagent for the quantitative release of covalently bound halogens for analytic determination ; Degradation of pesticides

pictograms

CorrosionEnvironment
GHS05,GHS09

signalword

Danger

hcodes

H314,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014,EUH019

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0873
BCCP0947
BCCN2422
BCCN0279
BCCN0278

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M.V. Kennedy et al.
Journal of Environmental Quality, 1, 63-63 (1972)
U. Goedde et al.
WLB, Wasser, Luft Boden, 35, 75-75 (1991)
Sodium biphenyl method for determination of covalently bound fluorine in organic compounds and biological materials.
P Venkateswarlu
Analytical chemistry, 54(7), 1132-1137 (1982-06-01)
Determination of Total Organic Fluorine (TOF) in environmental samples using flow-injection and chromatographic methods
Trojanowicz M, et al.
Analytical Methods : Advancing Methods and Applications, 3(5), 1039-1045 (2011)

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