146552
Benzyltriethylammonium chloride
99%, solid
Synonym(s):
BTEAC
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About This Item
Linear Formula:
C6H5CH2N(Cl)(C2H5)3
CAS Number:
Molecular Weight:
227.77
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
EC Number:
200-270-1
MDL number:
Beilstein/REAXYS Number:
3574984
Product Name
Benzyltriethylammonium chloride, 99%
Quality Level
assay
99%
form
solid
reaction suitability
core: ammonium
mp
190-192 °C (dec.) (lit.)
SMILES string
[Cl-].CC[N+](CC)(CC)Cc1ccccc1
InChI
1S/C13H22N.ClH/c1-4-14(5-2,6-3)12-13-10-8-7-9-11-13;/h7-11H,4-6,12H2,1-3H3;1H/q+1;/p-1
InChI key
HTZCNXWZYVXIMZ-UHFFFAOYSA-M
Application
Benzyltriethylammonium chloride is a lipophilic phase-transfer catalyst that can be used in phase-transfer catalysis (PTC) to catalyze polycondensation reactions to form high molecular weight polymers under bi-phasic conditions.
It can also be used:
It can also be used:
- To activate hydroxyapatite and natural phosphate for use as a solid support for Knoevenagel condensation and Claisen-Schmidt condensation, respectively at room temperature and in the absence of a solvent.
- To increase the efficiency of mCPBA oxidation of sulfonimine generated from arenesulfonamide and diethyl acetal of an aromatic aldehyde to form 2-sulfonyloxaziridines.
- In combination with antimony(V) chloride to form a catalytic system for the Friedel-Crafts acylation reactions of arenes with acyl and sulfonyl chlorides.
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signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
>527.0 °F - closed cup
flash_point_c
> 275 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Antimony (V) Chloride-Benzyltriethylammonium Chloride Complex as an Efficient Catalyst for Friedel- Crafts Acylation Reactions
Huang A-P, et al.
advanced synthesis and catalysis, 346(6), 599-602 (2004)
Preparation and properties of fluorine-containing polyarylates from tetrafluoroisophthaloyl chloride and bisphenols
Kakimoto M-A, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 25(10), 2747-2753 (1987)
Polymerization by phase transfer catalysis, 2 Polythiocarbonates by polymerization of Bisphenol A with thiophosgene
Tagle LH, et al.
Macromolecular Chemistry and Physics, 186(5), 915-921 (1985)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 146552-100G | 04061838736918 |
| 146552-25G | 04061838736925 |
| 146552-500G | 04061838736932 |