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Merck
CN

147443

3-Chloropropionyl chloride

technical grade

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About This Item

Linear Formula:
ClCH2CH2COCl
CAS Number:
625-36-5
Molecular Weight:
126.97
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24848553
EC Number:
210-890-4
Beilstein/REAXYS Number:
635814
MDL number:
MFCD00000747
Form:
liquid

Key Documents

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InChI key

INUNLMUAPJVRME-UHFFFAOYSA-N

InChI

1S/C3H4Cl2O/c4-2-1-3(5)6/h1-2H2

SMILES string

ClCCC(Cl)=O

grade

technical grade

form

liquid

Quality Level

100

bp

143-145 °C (lit.)

density

1.33 g/mL at 25 °C (lit.)

functional group

acyl chloride, chloro

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Application

3-Chloropropionyl chloride was used to modify hydrophilic and macroporous polymer resins composed of glycerylmethacrylate, styrene and divinylbenzene. It was used in the synthesis of diethylaminopropionamido-hydroxy-anthraquinones, which are potential anticancer agents.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

supp_hazards

EUH014

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

flash_point_f

158.9 °F - closed cup

flash_point_c

70.5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
STBG5236V
STBF4616V
STBF4118V
STBF3610V
STBF1361V

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M Hasegawa et al.
Biotechnology and bioengineering, 36(3), 219-223 (1990-07-01)
Hydrophilic and macroporous polymer resins composed of glycerylmethacrylate, styrene, and divinylbenzene were quite easily modified with isothiocyanate groups using a Friedel-Crafts reaction with 3-chloropropionyl chloride and subsequent nucleophilic reaction with KSCN. Alkaline phosphatase and trypsin could be covalently bound to
C Antonello et al.
Archiv der Pharmazie, 322(9), 541-544 (1989-09-01)
A number of new 9,10-anthracenediones were obtained, bearing one or two hydroxyl groups and one positively charged side chain at different positions of the aromatic ring system (compounds 1-5 in Chart 1). These derivatives resemble the anticancer agents mitoxantrone and

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