14804
1,2-Bis(dimethylsilyl)benzene
≥98.0%
Synonym(s):
o-Phenylenebis(dimethylsilane)
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About This Item
Linear Formula:
C6H4[SiH(CH3)2]2
CAS Number:
Molecular Weight:
194.42
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2937027
Assay:
≥98.0%
InChI
1S/C10H18Si2/c1-11(2)9-7-5-6-8-10(9)12(3)4/h5-8,11-12H,1-4H3
SMILES string
C[SiH](C)c1ccccc1[SiH](C)C
InChI key
QAUCEYVYCBYVDK-UHFFFAOYSA-N
assay
≥98.0%
refractive index
n20/D 1.51
bp
101 °C/13 mmHg (lit.)
density
0.898 g/mL at 25 °C (lit.)
Other Notes
Protecting group-reagent for amines and amino acids forming "benzostabase" derivatives, more acid-stable than "stabase" analogs; Reaction with olefins and ynes
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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F. Cavelier-Frontin et al.
Tetrahedron, 47, 9807-9807 (1991)
R.P. Bonar-Law et al
Tetrahedron Letters, 31, 6721-6721 (1990)
Tetrahedron, 47, 9807-9807 (1993)
M. Tanaka et al.
Organometallics, 10, 16-16 (1991)
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