149497
Methyl diphenylphosphinite
97%, liquid
Synonym(s):
Diphenylmethoxyphosphine, Methoxydiphenylphosphine, NSC 171167
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About This Item
Product Name
Methyl diphenylphosphinite, 97%
InChI key
OAADXJFIBNEPLY-UHFFFAOYSA-N
InChI
1S/C13H13OP/c1-14-15(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
SMILES string
COP(c1ccccc1)c2ccccc2
assay
97%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling
refractive index
n20/D 1.604 (lit.)
bp
149 °C/6 mmHg (lit.)
density
1.078 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
- Catalyst for hydroformylative desymmetrization of bisalkenyl carbinols and bishomoallylic carbinols
- Ligand in rhodium-catalyzed hydroformylation of bishomoallylic alcohols
- Calatyst in preparation of γ-lactones via branched-regioselective hydroformylation reactions
- Ligand for nickel-catalyzed hydrocyanation reactions
- Catalyst in annulation reactions
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
>235.4 °F - closed cup
flash_point_c
> 113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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