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Merck
CN

150533

Thallium(III) trifluoroacetate

technical grade

Synonym(s):

TTFA, Tris(trifluoroacetato)thallium, Thallic trifluoroacetate, Trifluoroacetic acid thallium(III) salt

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About This Item

Linear Formula:
(CF3COO)3Tl
CAS Number:
23586-53-0
Molecular Weight:
543.43
NACRES:
NA.22
PubChem Substance ID:
24849042
UNSPSC Code:
12161600
EC Number:
245-761-1
MDL number:
MFCD00000414

Key Documents

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InChI key

PSHNNUKOUQCMSG-UHFFFAOYSA-K

InChI

1S/3C2HF3O2.Tl/c3*3-2(4,5)1(6)7;/h3*(H,6,7);/q;;;+3/p-3

SMILES string

FC(F)(F)C(=O)O[Tl](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F

grade

technical grade

reaction suitability

core: thallium, reagent type: catalyst

mp

213 °C (dec.) (lit.)

storage temp.

2-8°C

Quality Level

100

Related Categories

Application

Oxidizing agent used in the synthesis of S-substituted cysteine peptides and proteins containing disulfide bonds.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
STBF4289V
STBC0984V
S51568
02127HJ
S51569

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Shenglong Zhu et al.
Nutrition and cancer, 72(4), 696-707 (2019-07-30)
Kudingcha is implicated in alleviating metabolic disorders in traditional Chinese medicine. However, the role of Kudingcha, one of the Ligustrum robustum species, in metabolic regulations and its antitumor activity in triple-negative breast cancer (TNBC) remains to be determined. Two breast
Luis Julià et al.
Magnetic resonance in chemistry : MRC, 49(4), 164-167 (2011-03-26)
Electron paramagnetic resonance (EPR) analysis of neutral and acidic solutions of 2,5-dimethyl-1-phenylpyrrol (1) and meta-, para-, and ortho-bis(2,5-dimethylpyrrol-1-yl)benzenes (4-6) in the presence of Tl(III) trifluoroacetate as oxidant reveals the poor stability of their generated monomeric radical cations which dimerize through
Rui Tang et al.
Journal of natural medicines, 74(2), 495-500 (2020-02-01)
Cancer cells adapted to the microenvironment in tumor such as hypoxic and nutrient-starved conditions are now paid much attention as the therapeutic target of cancer. In the course of search for selective cytotoxic substances against cancer cells adapted to nutrient
Tetrahedron, 44, 805-805 (1988)
Deacon, G. B.; Smith, R. N. M.
Journal of Fluorine Chemistry, 15, 85-85 (1980)
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Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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