152145
1,1-Diphenylethanol
98%
Synonym(s):
α-Methylbenzhydrol
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About This Item
Linear Formula:
CH3C(C6H5)2OH
CAS Number:
Molecular Weight:
198.26
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-970-1
MDL number:
Assay:
98%
Form:
solid
InChI key
GIMDPFBLSKQRNP-UHFFFAOYSA-N
InChI
1S/C14H14O/c1-14(15,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11,15H,1H3
SMILES string
CC(O)(c1ccccc1)c2ccccc2
assay
98%
form
solid
mp
77-81 °C (lit.)
functional group
hydroxyl, phenyl
Quality Level
Related Categories
Application
1,1-Diphenylethanol was used to study the ESR spectra of the spiro-cyclohexadienyl intermediate in the alkoxyl radicals.
General description
The H-bonds in 1,1-diphenylethanol were studied by means of infrared (IR) absorption spectra.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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K U Ingold et al.
The Journal of organic chemistry, 71(26), 9906-9908 (2006-12-16)
Grossi and Strazzari have reported (J. Org. Chem. 2000, 65, 2748-2754) that the ceric ammonium nitrate modulated photooxidation of triphenylmethanol and 1,1-diphenylethanol yielded ESR spectra of the putative spiro-cyclohexadienyl intermediates in the O-neophyl rearrangements of the corresponding alkoxyl radicals, Ph2(R)CO*
B Y Sultanli et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(6), 1121-1126 (2005-03-03)
The parameters of stretching vibrations nu(OH) (frequencies and integral intensities) have been calculated from IR spectra of a large number of H-complexes of 1,1-diphenylethanol [(C(6)H(5))(2)C(CH(3))OH] with solvents of various proton accepting strength which were not regularly reported. The data has
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