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Merck
CN

155721

Methacrylic acid

contains 250 ppm MEHQ as inhibitor, 99%

Synonym(s):

2-Methacrylic acid, 2-Methylpropenoic acid

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About This Item

Linear Formula:
H2C=C(CH3)COOH
CAS Number:
79-41-4
Molecular Weight:
86.09
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24849561
EC Number:
201-204-4
Beilstein/REAXYS Number:
1719937
MDL number:
MFCD00002651

Key Documents

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Product Name

Methacrylic acid, contains 250 ppm MEHQ as inhibitor, 99%

InChI key

CERQOIWHTDAKMF-UHFFFAOYSA-N

InChI

1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6)

SMILES string

C=C(C)C(O)=O

vapor density

>3 (vs air)

vapor pressure

1 mmHg ( 20 °C)

assay

99%

form

liquid

autoignition temp.

752 °F

contains

250 ppm MEHQ as inhibitor

refractive index

n20/D 1.431 (lit.)

pH

2.0-2.2 (20 °C, 100 g/L)

bp

163 °C (lit.)

mp

12-16 °C (lit.)

Quality Level

200

solubility

water: 98 g/L at 20 °C

density

1.015 g/mL at 25 °C (lit.)

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Application

MAA is used to synthesize poly(methacrylic acid)-g-poly(ε-caprolactone) copolymers, polymeric blends with PMMA and hydroxyethyl methacrylate (HEMA)-MAA hydrogels.

General description

Methacrylic acid (MAA) is an organic compound, colorless, viscous liquid. It is a monofunctional methacrylayte monomer. It is soluble in warm water and miscible in most organic solvents. MAA is used as a starting material for the production of its esters, especially methyl methacrylate and poly methyl methacrylate (PMMA).

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

152.6 °F - closed cup

flash_point_c

67 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCN7343
MKCX9348
SDBB3566
SDBB3565
MKCX0936

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Reversible Addition Fragmentation Chain Transfer
(RAFT) Polymerization
Moad G, et al.
Material Matters, 5(1) (2010)
Synthesis of graft copolymers of poly(methacrylic acid)-g-poly(?-caprolactone) by coupling ROP and RAFT polymerizations
Kiehl J, et al.
Polymer, 53(3), 694-700 (2012)
Thomas J Dursch et al.
Biomaterials, 35(2), 620-629 (2013-10-24)
Two-photon confocal microscopy and back extraction with UV/Vis-absorption spectrophotometry quantify equilibrium partition coefficients, k, for six prototypical drugs in five soft-contact-lens-material hydrogels over a range of water contents from 40 to 92%. Partition coefficients were obtained for acetazolamide, caffeine, hydrocortisone
Josué A Torres-Ávalos et al.
Polymers, 13(4) (2021-03-07)
Design of a smart drug delivery system is a topic of current interest. Under this perspective, polymer nanocomposites (PNs) of butyl acrylate (BA), methacrylic acid (MAA), and functionalized carbon nanotubes (CNTsf) were synthesized by in situ emulsion polymerization (IEP). Carbon
Alexandra Muñoz-Bonilla et al.
Polymers, 12(12) (2020-12-03)
Several hydrogels based on 2-hydroxyethyl methacrylate and a methacrylic monomer containing a thiazole group in its lateral chain have been prepared by thermal polymerization at 60 °C in water solution varying the chemical composition of the gels. The posterior quaternization
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RAFT Polymerization

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逆加成-断裂链转移 (RAFT)聚合

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