155764
o-Phenylene phosphorochloridite
97%, solid
Synonym(s):
2-Chloro-1,3,2-benzodioxaphosphole, o-Phenylene chlorophosphite, Chloro(1,2-phenylenedioxy)phosphine, Cyclic o-phenylene phosphorochloridite, Phosphorochloridous acid orthophenylene ester, Pyrocatechol phosphoryl chloride
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About This Item
Product Name
o-Phenylene phosphorochloridite, 97%
InChI key
YUJYEGDMJZHLMY-UHFFFAOYSA-N
InChI
1S/C6H4ClO2P/c7-10-8-5-3-1-2-4-6(5)9-10/h1-4H
SMILES string
ClP1Oc2ccccc2O1
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
refractive index
n20/D 1.571 (lit.)
bp
80 °C/20 mmHg (lit.)
mp
30-35 °C (lit.)
density
1.466 g/mL at 25 °C (lit.)
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Application
- Catalyst in synthesis of bakkane sesquiterpenes
- Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures
- Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts
- Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction
- Phosphorylation agent
- Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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