156051
1,1′-Thiocarbonyldiimidazole
technical grade, 90%
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About This Item
Empirical Formula (Hill Notation):
C7H6N4S
CAS Number:
Molecular Weight:
178.21
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-183-4
Beilstein/REAXYS Number:
609349
MDL number:
Assay:
90%
Product Name
1,1′-Thiocarbonyldiimidazole, technical grade, 90%
InChI key
RAFNCPHFRHZCPS-UHFFFAOYSA-N
InChI
1S/C7H6N4S/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H
SMILES string
S=C(n1ccnc1)n2ccnc2
grade
technical grade
assay
90%
reaction suitability
reaction type: Carbonylations
mp
98-102 °C (lit.)
functional group
thiourea
Quality Level
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Application
A useful reagent in biochemical synthesis.
Reagent used for the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Paweł Chochrek et al.
The Journal of organic chemistry, 72(14), 5276-5284 (2007-06-21)
1 alpha,25-Dihydroxyvitamin D3 (calcitriol, 1) is a bioregulator important for the treatment of various human metabolic diseases and biomedical research. Herein, we report an efficient diastereoselective approach to the key trans-hydrindane building block for calcitriol synthesis (2a) starting from the
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