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Sigma-Aldrich

2,3-Dimethyl-2,3-dinitrobutane

98%

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Linear Formula:
(CH3)2C(NO2)C(CH3)2NO2
CAS Number:
Molecular Weight:
176.17
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

solid

mp

214-215 °C (dec.) (lit.)

SMILES string

CC(C)([N+]([O-])=O)C(C)(C)[N+]([O-])=O

InChI

1S/C6H12N2O4/c1-5(2,7(9)10)6(3,4)8(11)12/h1-4H3

InChI key

DWCLXOREGBLXTD-UHFFFAOYSA-N

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D155624345482456144
form

solid

form

liquid

form

liquid

form

-

mp

214-215 °C (dec.) (lit.)

mp

-

mp

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Application

2,3-Dimethyl-2,3-dinitrobutane (DMNB) is an additive required for commercial plastic explosives. The product has been used to develop a fast, square-wave voltammetric measurement protocol of taggant (DMNB explosive) at an unmodified carbon fiber electrode. This protocol used a phosphate buffer solution at pH 7.0.

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 2 Oral

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Shasha Song et al.
Journal of fluorescence, 30(3), 717-723 (2020-05-10)
The coordination polymers based on Zn(II) ions and the metal nodes which has chemical formula of {[Zn3(L)2(tib)2(H2O)2]·(DMF)2}n (1) was synthesized via using 1,3,5-tris(1-imidazolyl)benzene (tib) and 2,6-di(4-carboxylphenyl)pyridine-4-carboxylic acid (H3L) as ligands under solvothermal conditions. Given its strong luminescent emission at room
Meaghan E Germain et al.
Inorganic chemistry, 46(11), 4422-4429 (2007-05-03)
Fluorescent sensors for the detection of chemical explosives are in great demand. It is shown herein that the fluorescence of ZnL* (H2L=N,N'-phenylene-bis-(3,5-di-tert-butylsalicylideneimine)) is quenched in solution by nitroaromatics and 2,3-dimethyl-2,3-dinitrobutane (DMNB), chemical signatures of explosives. The relationship between the structure
T V Reddy et al.
Journal of applied toxicology : JAT, 14(3), 231-232 (1994-05-01)
Female SENCAR mice initiated with 2,3-dimethyl-2,3-dinitrobutane (DMDNB) and promoted with 12-O-tetradecanoylphorol-13-acetate (TPA) via the SENCAR mouse skin bioassay did not exhibit a significant increase in skin tumors. The mice received 20 mg kg-1 DMDNB divided into six intragastric doses over
Sensitive Voltammetric Sensing of the 2,3-Dimethyl-2,3-dinitrobutane (Dmnb) Explosive Taggant
Wang JT, et al.
Electroanalysis, 18, 971-975 (2006)
Veerasamy Sathish et al.
Dalton transactions (Cambridge, England : 2003), 46(48), 16738-16769 (2017-11-11)
The detection of chemical explosives is a major area of research interest and is essential for the military as well as homeland security to counter the catastrophic effects of global terrorism. In recent years, tremendous effort has been devoted to

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