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157716

2,6-Diisopropylaniline

Name: 2,6-Diisopropylaniline
Brand: ALDRICH

technical grade, 90%

Synonym(s):

2,6-Bis(1-methylethyl)benzenamine, 2,6-Bis(propan-2-yl)aniline, 2,6-Diisopropylphenylamine

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About This Item

Linear Formula:

[(CH₃)₂CH]₂C₆H₃NH₂

CAS Number:

24544-04-5

Molecular Weight:

177.29

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24849695

EC Number:

246-305-4

Beilstein/REAXYS Number:

2208763

MDL number:

MFCD00008887

Assay:

90%

Form:

liquid

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Properties

grade

technical grade

Quality Level

100

vapor pressure

<0.01 mmHg ( 20 °C)

assay

90%

form

liquid

refractive index

n20/D 1.532 (lit.)

bp

257 °C (lit.)

mp

−45 °C (lit.)

density

0.94 g/mL at 25 °C (lit.)

SMILES string

CC(C)c1cccc(C(C)C)c1N

InChI

1S/C12H19N/c1-8(2)10-6-5-7-11(9(3)4)12(10)13/h5-9H,13H2,1-4H3

InChI key

WKBALTUBRZPIPZ-UHFFFAOYSA-N

Description

General description

2,6-Diisopropylaniline on condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione.

Application

2,6-Diisopropylaniline was used in the preparation of multitopic Schiff-base ligand precursors. It was also used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene.

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pictograms

GHS07

signalword

Warning

hcodes

H319,H412

pcodes

P273 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 2

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U-OAr2 and U-SAr2 bonding.

Balamurugan Vidjayacoumar et al.

Dalton transactions (Cambridge, England : 2003), 41(26), 8175-8189 (2012-05-09)

A rigid NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene (H(2)[TXA(2)], 1) was prepared by palladium-catalyzed coupling of 2,6-diisopropylaniline with 4,5-dibromo-2,7-di-tert-butyl-9,9-dimethylthioxanthene. Deprotonation of 1 using (n)BuLi provided Li(2)(DME)(2)[TXA(2)] (2), and subsequent reaction with UCl(4) afforded [Li(DME)(3)][(TXA(2))UCl(3)] (4). The analogous NON-donor ligated complex [(XA(2))UCl(3)K(DME)(3)] [3; XA(2)

Synthesis and catalytic activity of heterogeneous rare-earth metal catalysts coordinated with multitopic Schiff-base ligands.

Yilin Sun et al.

Dalton transactions (Cambridge, England : 2003), 41(32), 9682-9688 (2012-07-12)

Four multitopic Schiff-base ligand precursors were synthesized via condensation of 4,4'-diol-3,3'-diformyl-1,1'-diphenyl or 1,3,5-tris(4-hydroxy-5-formylphenyl)benzene with 2,6-diisopropylaniline or 2,6-dimethylaniline. Amine elimination reactions of Ln[N(SiMe(3))(2)](3) (Ln = La, Nd, Sm or Y) with these multitopic ligand precursors gave ten heterogeneous rare-earth metal catalysts.

Remote activation of nickel catalysts for ethylene oligomerization.

Yaofeng Chen et al.

Angewandte Chemie (International ed. in English), 44(7), 1108-1112 (2005-01-13)

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Global Trade Item Number

SKU	GTIN
157716-100ML	04061838743527
157716-500ML	04061838743534