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157759

Sulfur monochloride

Name: Sulfur monochloride
Brand: ALDRICH

98%

Synonym(s):

Sulfur chloride

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About This Item

Linear Formula:

S₂Cl₂

CAS Number:

10025-67-9

Molecular Weight:

135.04

NACRES:

NA.23

PubChem Substance ID:

24849698

UNSPSC Code:

12352302

EC Number:

233-036-2

MDL number:

MFCD00011446

Assay:

98%

Form:

liquid

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Properties

vapor density

4.7 (vs air)

Quality Level

200

vapor pressure

6.8 mmHg ( 20 °C)

assay

98%

form

liquid

autoignition temp.

451 °F

refractive index

n20/D 1.658 (lit.)

bp

138 °C (lit.)

mp

−80 °C (lit.)

density

1.688 g/mL at 25 °C (lit.)

SMILES string

ClSSCl

InChI

1S/Cl2S2/c1-3-4-2

InChI key

PXJJSXABGXMUSU-UHFFFAOYSA-N

Description

General description

Sulfur monochloride is a yellowish-red liquid widely used as a reagent and intermediate in organic synthesis. It is also employed in manufacturing pesticides, pharmaceuticals, and dyes.

Application

Sulfur monochloride can be used:

To synthesize functionalized aryl and heteroaryl disulfides from functionalized zinc organometallics.
As a reagent to prepare heterocycles with various numbers of sulfur atoms.
As a cross-linking agent to prepare rubber aerogels with enhanced thermal stability.
Toprepare macroporous cryogels of polyisobutylene and silica nanoparticles.

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pictograms

GHS06,GHS05,GHS09

signalword

Danger

hcodes

H301 + H331,H314,H400

pcodes

P261 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Skin Corr. 1A

supp_hazards

EUH014,EUH029

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Articles

Methods of Synthesizing Monodisperse Colloidal Quantum Dots

Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.

A direct preparation of functionalized aryl and heteroaryl disulfides from functionalized zinc organometallics by using sulfur monochloride (S2Cl2

Tobias J Korn and Paul Knochel

Synlett, 2005, 1185-1187 (2005)

Janus Nanostructures from ABC/B Triblock Terpolymer Blends.

Andrea Steinhaus et al.

Polymers, 11(7) (2019-07-03)

Lamella-forming ABC triblock terpolymers are convenient building blocks for the synthesis of soft Janus nanoparticles (JNPs) by crosslinking the B domain that is "sandwiched" between A and C lamellae. Despite thorough synthetic variation of the B fraction to control the

Hierarchically Macroporous Cryogels of Polyisobutylene and Silica Nanoparticles

Deniz C. Tuncaboylu and Oguz Okay

Langmuir, 26, 7574-7581 (2010)

View All Related Papers

Global Trade Item Number

SKU	GTIN
157759-250G	04061838743565
157759-PZ	04061823848206
157759-1KG	04061838137753
157759-50G	04061838137760