159239
2-Bromoanisole
97%
Synonym(s):
1-Bromo-2-methoxybenzene
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About This Item
Linear Formula:
BrC6H4OCH3
CAS Number:
Molecular Weight:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-425-8
Beilstein/REAXYS Number:
1859996
MDL number:
Assay:
97%
Form:
liquid
Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.573 (lit.)
bp
223 °C (lit.)
mp
2 °C (lit.)
density
1.502 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
COc1ccccc1Br
InChI
1S/C7H7BrO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
InChI key
HTDQSWDEWGSAMN-UHFFFAOYSA-N
General description
Diffusion coefficients of 2-bromoanisole at infinite dilution in supercritical carbon dioxide has been evaluated by Taylor-Aris chromatographic technique.
Application
2-Bromoanisole was used in the synthesis of unsymmetrically substituted biphenyl compounds. It was also used in the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3).
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Gloves
Regulatory Information
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Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1, 3-divinylbenzene at infinite dilution in supercritical carbon dioxide
Suarez-Iglesias O, et al.
Fluid Phase Equilibria, 260(2), 279-286 (2007)
Burns et al.
The Journal of organic chemistry, 65(17), 5185-5196 (2000-09-19)
A general strategy for the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3) in 6-steps (starting from 2-bromoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacyclophane ring in good to moderate yield is described.
Marta Elsheimer-Matulova et al.
Veterinary research, 51(1), 67-67 (2020-05-15)
In attempt to identify genes that are induced in chickens by Salmonella Enteritidis we identified a new highly inducible gene, interleukin 4 induced 1 gene (IL4I1). IL4I1 reached its peak expression (458× induction) in the cecum of newly hatched chickens 4 days
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 159239-100G | 04061838744449 |
| 159239-25G | 04061838744456 |