159239
2-Bromoanisole
97%
Synonym(s):
1-Bromo-2-methoxybenzene
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About This Item
Linear Formula:
BrC6H4OCH3
CAS Number:
Molecular Weight:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-425-8
Beilstein/REAXYS Number:
1859996
MDL number:
Product Name
2-Bromoanisole, 97%
InChI key
HTDQSWDEWGSAMN-UHFFFAOYSA-N
InChI
1S/C7H7BrO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
SMILES string
COc1ccccc1Br
assay
97%
form
liquid
refractive index
n20/D 1.573 (lit.)
bp
223 °C (lit.)
mp
2 °C (lit.)
density
1.502 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
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Application
2-Bromoanisole was used in the synthesis of unsymmetrically substituted biphenyl compounds. It was also used in the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3).
General description
Diffusion coefficients of 2-bromoanisole at infinite dilution in supercritical carbon dioxide has been evaluated by Taylor-Aris chromatographic technique.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Gloves
Regulatory Information
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Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1, 3-divinylbenzene at infinite dilution in supercritical carbon dioxide
Suarez-Iglesias O, et al.
Fluid Phase Equilibria, 260(2), 279-286 (2007)
Burns et al.
The Journal of organic chemistry, 65(17), 5185-5196 (2000-09-19)
A general strategy for the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3) in 6-steps (starting from 2-bromoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacyclophane ring in good to moderate yield is described.
Marta Elsheimer-Matulova et al.
Veterinary research, 51(1), 67-67 (2020-05-15)
In attempt to identify genes that are induced in chickens by Salmonella Enteritidis we identified a new highly inducible gene, interleukin 4 induced 1 gene (IL4I1). IL4I1 reached its peak expression (458× induction) in the cecum of newly hatched chickens 4 days
Patrick T Weiser et al.
Bioorganic & medicinal chemistry, 22(2), 917-926 (2013-12-24)
A series of unsymmetrically substituted biphenyl compounds was designed as alpha helical proteomimetics with the aim of inhibiting the binding of coactivator proteins to the nuclear hormone receptor coactivator binding domain. These compounds were synthesized in good overall yields in
Hana Štěpánová et al.
Toxins, 12(10) (2020-10-01)
Deoxynivalenol (DON)-contaminated feed represents a serious problem for pigs due to their high sensitivity to its toxicological effects. The aim of the present study was to evaluate the impact of intrauterine DON exposure on the immune system of piglets. Pure
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